Technology Process of C35H44N2O5Si
There total 11 articles about C35H44N2O5Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C35H42N2O6Si;
With
2,6-di-tert-butyl-pyridine; trimethoxonium tetrafluoroborate;
In
dichloromethane;
at 25 ℃;
for 12h;
Inert atmosphere;
With
sodium tetrahydroborate;
In
methanol; dichloromethane;
at 0 ℃;
for 0.75h;
Inert atmosphere;
DOI:10.1021/ja500548e
- Guidance literature:
-
C35H42N2O5SSi;
With
2,6-di-tert-butyl-pyridine; trimethoxonium tetrafluoroborate;
In
dichloromethane;
at 25 ℃;
for 12h;
Inert atmosphere;
With
sodium tetrahydroborate;
In
methanol;
at 0 ℃;
for 0.75h;
DOI:10.1021/ja500548e
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: acetic acid; sodium cyanoborohydride / isopropyl alcohol / 16 h / 25 °C
2.1: hydrogen
3.1: ChiralCel OD column / isopropyl alcohol; hexane / Resolution of racemate
4.1: 1H-imidazole; sodium hydride / tetrahydrofuran; mineral oil / 0 - 25 °C
4.2: 1 h / 0 - 25 °C
4.3: 1 h / 0 - 25 °C
5.1: toluene / 36 h / 150 °C
6.1: lithium diisopropyl amide / tetrahydrofuran / 0.5 h / -78 °C
6.2: 2.5 h / -78 °C
7.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / -78 - 25 °C
8.1: 2,6-di-tert-butyl-pyridine; trimethoxonium tetrafluoroborate / dichloromethane / 12 h / 25 °C / Inert atmosphere
8.2: 0.75 h / 0 °C / Inert atmosphere
With
1H-imidazole; 2,6-di-tert-butyl-pyridine; hydrogen; trimethoxonium tetrafluoroborate; sodium hydride; sodium cyanoborohydride; acetic acid; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide;
In
tetrahydrofuran; hexane; dichloromethane; isopropyl alcohol; toluene; mineral oil;
DOI:10.1021/ja500548e
