[PPh₄][Fe(2,6-di-tert-2-[(pentafluorophenyl)amino]benzenethiol^(2-))2]

Base Information

• Chemical Name: [PPh₄][Fe(2,6-di-tert-2-[(pentafluorophenyl)amino]benzenethiol^(2-))2]
• CAS No.: 1085473-63-7
• Molecular Formula: C₂₄H₂₀P*C₄₀H₄₀F₁₀FeN₂S₂
• Molecular Weight: 1198.13
• Mol file: 1085473-63-7.mol

Synonyms:[PPh₄][Fe(2,6-di-tert-2-[(pentafluorophenyl)amino]benzenethiol^(2-))2]

Chemical Property of [PPh₄][Fe(2,6-di-tert-2-[(pentafluorophenyl)amino]benzenethiol^(2-))2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PPh₄][Fe(2,6-di-tert-2-[(pentafluorophenyl)amino]benzenethiol^(2-))2]

There total 1 articles about [PPh₄][Fe(2,6-di-tert-2-[(pentafluorophenyl)amino]benzenethiol^(2-))2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

4,6-di-tert-butyl-2-[(pentafluorophenyl)amino]benzenethiol (1085473-65-9) + tetraphenylphosphonium bromide (2751-90-8) + iron(II) bromide (7789-46-0) → [PPh4][Fe(2,6-di-tert-2-[(pentafluorophenyl)amino]benzenethiol(2-))2] (1085473-63-7)

Guidance literature:

With triethylamine; In acetonitrile; FeBr2 and Et3N slowly added to soln. of thiol in MeCN at 20°C with stirring under Ar, soln. exposed to air, evapd. under vac., CH2Cl2 added, Ph4PBr added at 20°C with stirring under Ar; soln. filtered through Celite, filtrate concd. under vac., n-hexane added, ppt. filtered off; elem. anal.;

DOI:10.1021/ic801109n

Reference yield: 51.0%

[PPh4][Fe(2,6-di-tert-2-[(pentafluorophenyl)amino]benzenethiol(2-))2] (1085473-63-7) + iodine (7553-56-2,12190-71-5,8031-47-8) → [FeI(2,6-di-tert-2-[(pentafluorophenyl)amino]benzenethiol(1-))2]

Guidance literature:

In hexane; dichloromethane; under Ar; soln. of I2 in n-hexane added to soln. of Fe complex in CH2Cl2, mixt. stirred for 20 min; evapd. under vac., residue dissolved in Et2O, soln. filtered through Celite, filtrate evapd. under vac.; elem. anal.;

DOI:10.1021/ic801109n

upstream raw materials:

4,6-di-tert-butyl-2-[(pentafluorophenyl)amino]benzenethiol

tetraphenylphosphonium bromide

iron(II) bromide