C₃₈H₅₃NO₄

Base Information

• Chemical Name: C₃₈H₅₃NO₄
• CAS No.: 1276112-44-7
• Molecular Formula: C₃₈H₅₃NO₄
• Molecular Weight: 587.843
• Mol file: 1276112-44-7.mol

Synonyms:C₃₈H₅₃NO₄

Chemical Property of C₃₈H₅₃NO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₈H₅₃NO₄

There total 22 articles about C₃₈H₅₃NO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

C43H61NO6 (1276112-43-6) → C38H53NO4 (1276112-44-7)

Guidance literature:

With hydrogenchloride; In methanol; water; at 20 ℃; for 12h;

DOI:10.1016/j.tetlet.2011.01.018

Reference yield:

C27H29NO5 (1308271-86-4) → C38H53NO4 (1276112-44-7)

Guidance literature:

Multi-step reaction with 14 steps

1: silver(l) oxide / N,N-dimethyl-formamide / 24 h / 20 °C

2: ammonium cerium (IV) nitrate / water; acetonitrile / 2.5 h / 0 - 20 °C

3: dmap; triethylamine / dichloromethane / 2 h / 0 °C

4: tetrahydrofuran / 1.5 h / -78 °C

5: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 2 h / 0 °C

6: pyridine / 12 h / 0 - 20 °C

7: tetrakis(triphenylphosphine) palladium⁽⁰⁾; ammonium formate; triethylamine / toluene / 0.5 h / Reflux

8: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone; tert-butyl alcohol / 24 h / 20 °C

9: sodium periodate / tetrahydrofuran; water / 3.5 h / 0 - 20 °C

10: t-butyldimethylsiyl triflate / toluene / 9 h / -78 °C

11: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone; tert-butyl alcohol / 24 h / 20 °C

12: sodium periodate / tetrahydrofuran; water / 4 h / 0 - 20 °C

13: tetrahydrofuran / 4.5 h / -78 - 0 °C / Inert atmosphere

14: hydrogenchloride / methanol; water / 12 h / 20 °C

With pyridine; hydrogenchloride; dmap; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; ammonium cerium (IV) nitrate; cerium(III) chloride heptahydrate; t-butyldimethylsiyl triflate; ammonium formate; 4-methylmorpholine N-oxide; triethylamine; silver(l) oxide; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; tert-butyl alcohol;

DOI:10.1016/j.tetlet.2011.01.018

Reference yield:

C34H35NO5 (1276112-28-7) → C38H53NO4 (1276112-44-7)

Guidance literature:

Multi-step reaction with 13 steps

1: ammonium cerium (IV) nitrate / water; acetonitrile / 2.5 h / 0 - 20 °C

2: dmap; triethylamine / dichloromethane / 2 h / 0 °C

3: tetrahydrofuran / 1.5 h / -78 °C

4: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 2 h / 0 °C

5: pyridine / 12 h / 0 - 20 °C

6: tetrakis(triphenylphosphine) palladium⁽⁰⁾; ammonium formate; triethylamine / toluene / 0.5 h / Reflux

7: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone; tert-butyl alcohol / 24 h / 20 °C

8: sodium periodate / tetrahydrofuran; water / 3.5 h / 0 - 20 °C

9: t-butyldimethylsiyl triflate / toluene / 9 h / -78 °C

10: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone; tert-butyl alcohol / 24 h / 20 °C

11: sodium periodate / tetrahydrofuran; water / 4 h / 0 - 20 °C

12: tetrahydrofuran / 4.5 h / -78 - 0 °C / Inert atmosphere

13: hydrogenchloride / methanol; water / 12 h / 20 °C

With pyridine; hydrogenchloride; dmap; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; ammonium cerium (IV) nitrate; cerium(III) chloride heptahydrate; t-butyldimethylsiyl triflate; ammonium formate; 4-methylmorpholine N-oxide; triethylamine; In tetrahydrofuran; methanol; dichloromethane; water; acetone; toluene; acetonitrile; tert-butyl alcohol;

DOI:10.1016/j.tetlet.2011.01.018

upstream raw materials:

C₂₇H₂₇NO₅

C₂₇H₂₉NO₅

C₃₄H₃₅NO₅

C₂₆H₂₇NO₄