Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine

Base Information

Chemical Name:Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine
CAS No.:173069-28-8
Molecular Formula:C₂₃H₃₃NOSi
Molecular Weight:367.607
Hs Code.:

Synonyms:Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine

Suppliers and Price of Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine

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Technology Process of Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine

There total 1 articles about Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (S)-3-tert-butyldimethylsilyloxy-4-phenyl-2-butanone

: 100-46-9
benzylamine

: 173069-28-8
Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine

Guidance literature:: With titanium tetrachloride; at -78 ℃;
DOI:10.1039/c39950002327

Reference yield: 70.0%

: 19810-31-2
Benzyloxyacetyl chloride

: 173069-28-8
Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine

: 187332-36-1
(3S,4S)-1-Benzyl-3-benzyloxy-4-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-ethyl]-4-methyl-azetidin-2-one

Guidance literature:: With triethylamine; In dichloromethane; at -78 - 20 ℃; for 20h;
DOI:10.1021/jo962017z

Reference yield:

: 173069-28-8
Benzyl-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-phenyl-prop-(Z)-ylidene]-amine

: 173069-37-9
(3S,4S)-1-benzyl-4-<(1S)-1-<(tert-butyldimethylsilyl)oxy>-2-phenylethyl>-3-hydroxy-4-methylazetidin-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / NEt₃ / CH₂Cl₂ / 20 h / -78 - 20 °C

2: 92 percent / NH₄HCO₂ / 10percent Pd on carbon / methanol / 1 h / Heating

With ammonium formate; triethylamine; palladium on activated charcoal; In methanol; dichloromethane;
DOI:10.1021/jo962017z