C₇₄H₉₀N₆O₈

Base Information

• Chemical Name: C₇₄H₉₀N₆O₈
• CAS No.: 1239184-55-4
• Molecular Formula: C₇₄H₉₀N₆O₈
• Molecular Weight: 1191.56
• Mol file: 1239184-55-4.mol

Synonyms:C₇₄H₉₀N₆O₈

Chemical Property of C₇₄H₉₀N₆O₈

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₇₄H₉₀N₆O₈

There total 6 articles about C₇₄H₉₀N₆O₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

3-(azidomethyl)-5-(tert-butyl)-2-hydroxybenzaldehyde (1238709-25-5) + 5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-dipropargylcalix[4]arene (139214-28-1) → C74H90N6O8 (1239184-55-4)

Guidance literature:

With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In dichloromethane; water; tert-butyl alcohol; at 20 ℃; for 12h;

DOI:10.1021/jo500892r

Reference yield: 89.91%

5,11,17,23-tetra-t-butyl-25,26,27,28-tetrahydroxycalix-4-arene (157432-87-6,288302-11-4,288302-12-5,60705-62-6) + 3-(azidomethyl)-5-(tert-butyl)-2-hydroxybenzaldehyde (1238709-25-5) + propargyl bromide (106-96-7) → C74H90N6O8 (1239184-55-4)

Guidance literature:

5,11,17,23-tetra-t-butyl-25,26,27,28-tetrahydroxycalix-4-arene; propargyl bromide; With potassium carbonate; In acetone; for 16h;

3-(azidomethyl)-5-(tert-butyl)-2-hydroxybenzaldehyde; With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In dichloromethane; water; tert-butyl alcohol; at 20 ℃; for 12h;

DOI:10.1039/c4dt01726a

Reference yield:

para-tert-butylphenol (98-54-4) → C74H90N6O8 (1239184-55-4)

Guidance literature:

Multi-step reaction with 4 steps

1: tributyl-amine; tin(IV) chloride / toluene / Reflux

2: hydrogenchloride / water / 24 h / 20 °C

3: sodium azide / N,N-dimethyl-formamide / 12 h / 20 °C

4: copper(ll) sulfate pentahydrate; sodium L-ascorbate / dichloromethane; water / 12 h / 20 °C

With hydrogenchloride; sodium azide; copper(ll) sulfate pentahydrate; tributyl-amine; tin(IV) chloride; sodium L-ascorbate; In dichloromethane; water; N,N-dimethyl-formamide; toluene;

DOI:10.1002/chem.201102791

upstream raw materials:

3-(azidomethyl)-5-(tert-butyl)-2-hydroxybenzaldehyde

5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-dipropargylcalix[4]arene

para-tert-butylphenol

2-hydroxy-5-t-butylbenzaldehyde

Downstream raw materials:

C₈₂H₁₀₈N₈O₆

C₈₈H₁₀₆N₁₀O₆

C₈₄H₁₀₀N₈O₆S₂

((CH₃)3CC₆H₂CH₂O)4H₂(CH₂C₂HN₃CH₂C₆H₂(C(CH₃)3)(OH)CHNCH₂C₅H₄N)2