6,13-diphenyl-5,14-dihydropentacene

Base Information

• Chemical Name: 6,13-diphenyl-5,14-dihydropentacene
• CAS No.: 861013-84-5
• Molecular Formula: C₃₄H₂₄
• Molecular Weight: 432.565
• Mol file: 861013-84-5.mol

Synonyms:6,13-diphenyl-5,14-dihydropentacene

Chemical Property of 6,13-diphenyl-5,14-dihydropentacene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6,13-diphenyl-5,14-dihydropentacene

There total 6 articles about 6,13-diphenyl-5,14-dihydropentacene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

6,13-diiodo-5,14-dihydropentacene (1333867-44-9) + phenylzinc chloride (28557-00-8) → 6,13-diphenyl-5,14-dihydropentacene (861013-84-5)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; for 12h; Temperature; Time; Reflux;

Reference yield:

6,13-diphenyl-pentacene (76727-11-2) → 6,13-diphenyl-5,14-dihydropentacene (861013-84-5)

Guidance literature:

With 1,4-dioxane; nickel; at 95 - 100 ℃;

DOI:10.1021/ja01258a005

Reference yield:

6,13-diphenyl-pentacene (76727-11-2) → 6,13-diphenyl-5,14-dihydropentacene (861013-84-5) + 6,13-diphenyl-1,4-dihydro-pentacene (861013-86-7)

Guidance literature:

With 1,4-dioxane; nickel; at 95 - 100 ℃; Hydrogenation;

DOI:10.1021/ja01258a005

upstream raw materials:

6,13-diphenyl-pentacene

1,4-dioxane

6,13-diiodo-5,14-dihydropentacene

phenylzinc chloride

Downstream raw materials:

6,13-diphenyl-pentacene

6,13-diphenyl-5,7,12,14-tetrahydro-pentacene

Refernces

• 1、 -. "6,13-DIHALOGEN-5,14-DIHYDROPENTACENE DERIVATIVE AND METHOD FOR PRODUCING 6,13-SUBSTITUTED-5,14-DIHYDROPENTACENE DERIVATIVE USING SAME". Paragraph 0160; 0161. . Retrieved 2013/04/10.