tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane
CAS No.:750646-33-4
Molecular Formula:C₂₇H₄₀O₃Si
Molecular Weight:440.698
Hs Code.:

Synonyms:tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane

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Technology Process of tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane

There total 1 articles about tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 455949-00-5
(2S,3S,4S)-3-(methoxymethoxy)-2,4-dimethylhept-6-en-1-ol

: 750646-33-4
tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 17h;
DOI:10.1002/chem.200305543

Reference yield: 86.0%

: 750646-33-4
tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane

: 750646-34-5
(4S,5S,6S)-7-(tert-Butyl-diphenyl-silanyloxy)-5-methoxymethoxy-4,6-dimethyl-heptan-1-ol

Guidance literature:: tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 20 ℃; for 15h;

With sodium hydroxide; dihydrogen peroxide; at 20 ℃; for 24h;
DOI:10.1002/chem.200305543

Reference yield:

: 750646-33-4
tert-Butyl-((2S,3S,4S)-3-methoxymethoxy-2,4-dimethyl-hept-6-enyloxy)-diphenyl-silane

: 750646-39-0
(2R,3S,6S,7S,8S)-9-(tert-Butyl-diphenyl-silanyloxy)-3,7-bis-methoxymethoxy-2,6,8-trimethyl-nonanoic acid methoxy-methyl-amide

Guidance literature:: Multi-step reaction with 5 steps

1.1: 9-BBN / tetrahydrofuran / 15 h / 20 °C

1.2: 86 percent / aq. NaOH; H₂O₂ / 24 h / 20 °C

2.1: Dess-Martin periodinane; NaHCO₃ / CH₂Cl₂

3.1: Bu₂BOTf; (i-Pr)2NEt / CH₂Cl₂ / 0.75 h / 0 °C

3.2: CH₂Cl₂ / 1.5 h / -78 - 20 °C

3.3: 486 mg / H₂O₂ / CH₂Cl₂ / pH 7

4.1: Me₃Al / toluene; tetrahydrofuran / 0.5 h / 20 °C

4.2: 84 percent / toluene; tetrahydrofuran / 15 h / -20 - 0 °C

5.1: 171 mg / (i-Pr)2NEt / CH₂Cl₂ / 20 h / 0 - 20 °C

With 9-borabicyclo[3.3.1]nonane dimer; di-n-butylboryl trifluoromethanesulfonate; trimethylaluminum; sodium hydrogencarbonate; Dess-Martin periodane; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1002/chem.200305543