1,2-Bis-(4-methoxyphenyl)-o-carborane

Base Information

• Chemical Name: 1,2-Bis-(4-methoxyphenyl)-o-carborane
• CAS No.: 37100-45-1
• Molecular Formula: C16H24 B10 O2
• Molecular Weight: 0
• Mol file: 37100-45-1.mol

Synonyms:1,2-Bis(4-methoxyphenyl)-1,2-dicarbadodecaborane(12)

Chemical Property of 1,2-Bis-(4-methoxyphenyl)-o-carborane

Chemical Property:

• PSA: 18.46000
• LogP: -0.54520

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-Bis-(4-methoxyphenyl)-o-carborane

There total 5 articles about 1,2-Bis-(4-methoxyphenyl)-o-carborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

1,2-dicarba-closo-dodecaborane(12) (16872-09-6) + para-iodoanisole (696-62-8) → 1,2-C2B10H10-1,2-(C6H4-4'-OCH3)2 (37100-45-1)

Guidance literature:

1,2-dicarba-closo-dodecaborane⁽¹²⁾; With isopropylmagnesium chloride; In tetrahydrofuran; at 0 - 20 ℃; for 12h; Inert atmosphere;

para-iodoanisole; With nickel dichloride; In toluene; at 100 ℃; for 6h; Inert atmosphere;

DOI:10.1002/anie.201502502

Reference yield: 34.0%

nido-decaborane (17702-41-9) + 4,4'-dimethoxydiphenylacetylene (2132-62-9) → 1,2-C2B10H10-1,2-(C6H4-4'-OCH3)2 (37100-45-1)

Guidance literature:

nido-decaborane; In acetonitrile; at 95 ℃; for 2h; Inert atmosphere;

4,4'-dimethoxydiphenylacetylene; In toluene; acetonitrile; at 95 ℃; for 17h; Inert atmosphere;

DOI:10.1039/d0ra07264h

Reference yield:

4,4'-dimethoxydiphenylacetylene (2132-62-9) → 1,2-C2B10H10-1,2-(C6H4-4'-OCH3)2 (37100-45-1)

Guidance literature:

With silver nitrate; In toluene; at 100 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201904940

upstream raw materials:

nido-decaborane

4,4'-dimethoxydiphenylacetylene

1,2-dicarba-closo-dodecaborane⁽¹²⁾

para-iodoanisole

Downstream raw materials:

1,2-C₂B₁₀H₁₀-1,2-(C₆H₄OCOC₆H₅)2

1,2-C₂B₁₀H₁₀-1,2-(C₆H₄-4'-OH)2