(CH3)5CpZr(μ-OCH2Ph2P)2(μ-Cl)2RhCO

Base Information

Chemical Name:(CH3)5CpZr(μ-OCH2Ph2P)2(μ-Cl)2RhCO
CAS No.:105900-17-2
Molecular Formula:C₃₇H₃₉Cl₂O₃P₂RhZr
Molecular Weight:858.698
Hs Code.:

Synonyms:(CH3)5CpZr(μ-OCH2Ph2P)2(μ-Cl)2RhCO

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Chemical Property of (CH3)5CpZr(μ-OCH2Ph2P)2(μ-Cl)2RhCO

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Technology Process of (CH3)5CpZr(μ-OCH2Ph2P)2(μ-Cl)2RhCO

There total 3 articles about (CH3)5CpZr(μ-OCH2Ph2P)2(μ-Cl)2RhCO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: di(rhodium)tetracarbonyl dichloride

: 105900-15-0
(C₅(CH₃)5)Zr(CH₃)(OCH₂P(C₆H₅)2)2

: 105900-16-1
(CH3)5CpZr(μ-OCH2Ph2P)2(μ2-η2-OC(CH3))(μ-Cl)RhCO

: 105900-17-2
(CH3)5CpZr(μ-OCH2Ph2P)2(μ-Cl)2RhCO

Guidance literature:: In toluene; byproducts: CO; To a flask contg. Zr and Rh complexes is distilled toluene at -78°C. After warming to 25°C the mixture is stirred for 1 h.; addn. of ether, filtn. at -78°C, washing, drying in vacuo yields μ2-η2-acetyl compound; μ2-Cl compound from filtrate after drying, refluxing in CHCl3 under Ar in the dark for 1.5 h, addn. of ether, filtn., drying under vac.; elem. anal.;

Reference yield: 68.0%

: 105900-16-1
(CH3)5CpZr(μ-OCH2Ph2P)2(μ2-η2-OC(CH3))(μ-Cl)RhCO

: 105900-17-2
(CH3)5CpZr(μ-OCH2Ph2P)2(μ-Cl)2RhCO

Guidance literature:: With hydrogenchloride; In dichloromethane; byproducts: acetaldehyde; elem. anal.;
DOI:10.1021/ja00286a045

Reference yield: 61.0%

: 105900-16-1
(CH3)5CpZr(μ-OCH2Ph2P)2(μ2-η2-OC(CH3))(μ-Cl)RhCO

: 105900-17-2
(CH3)5CpZr(μ-OCH2Ph2P)2(μ-Cl)2RhCO

: 75-07-0,9002-91-9
acetaldehyde

Guidance literature:: With HCl; In dichloromethane; cyclohexane; To a flask contg. complex is distilled CH2Cl2 at -78°C. Cyclohexane and HCl are condensed in at -196°C, the mixture is thawed, and stirred at room temp. for 4 days.; volatiles are pumped off, collected at -78°C, and analyzed by GC/MS and (1)H-NMR; highest concn. of intermediate is observed after 3.5 h;