3,5-Methanocyclopenta[b]pyrrole-6a(1H)-carboxylicacid,hexahydro-2-oxo-(9CI)

Base Information

Chemical Name:3,5-Methanocyclopenta[b]pyrrole-6a(1H)-carboxylicacid,hexahydro-2-oxo-(9CI)
CAS No.:286456-64-2
Molecular Formula:C₉H₁₁NO₃
Molecular Weight:181.191
Hs Code.:
Mol file:286456-64-2.mol

Synonyms:3,5-Methanocyclopenta[b]pyrrole-6a(1H)-carboxylicacid,hexahydro-2-oxo-(9CI)

Suppliers and Price of 3,5-Methanocyclopenta[b]pyrrole-6a(1H)-carboxylicacid,hexahydro-2-oxo-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 3,5-Methanocyclopenta[b]pyrrole-6a(1H)-carboxylicacid,hexahydro-2-oxo-(9CI)

Chemical Property:

Melting Point:302-305 °C (decomp)
Boiling Point:468.6±28.0 °C(Predicted)
PKA:3.57±0.20(Predicted)
PSA：69.89000
Density:1.494±0.06 g/cm3(Predicted)
LogP:0.26160

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 3,5-Methanocyclopenta[b]pyrrole-6a(1H)-carboxylicacid,hexahydro-2-oxo-(9CI)

There total 8 articles about 3,5-Methanocyclopenta[b]pyrrole-6a(1H)-carboxylicacid,hexahydro-2-oxo-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: C₁₁H₁₄N₂O₄

: 286456-64-2
(1S,3R,6S,7R)-5-Oxo-4-aza-tricyclo[4.2.1.0^3,7]nonane-3-carboxylic acid

Guidance literature:: With barium dihydroxide; In water; for 20h; Heating;
DOI:10.1071/CH03202

Reference yield: 25.0%

: 42392-37-0
(+/-)-6-oxobicyclo<2.2.1>heptane-endo-2-carboxylic acid

: 143-33-9,25596-52-5
sodium cyanide

: 286456-64-2
(1S,3R,6S,7R)-5-Oxo-4-aza-tricyclo[4.2.1.0^3,7]nonane-3-carboxylic acid

Guidance literature:: With ammonia; ammonium chloride; In water; for 5h; Heating;
DOI:10.1071/CH03202

Reference yield:

: 934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7,120-74-1
5-norbornene-endo-2-carboxylic acid

: 286456-64-2
(1S,3R,6S,7R)-5-Oxo-4-aza-tricyclo[4.2.1.0^3,7]nonane-3-carboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 35 percent / NaHCO₃; Br₂ / H₂O / 16 h

2: 45 percent / KOH / methanol; H₂O / 6 h / Heating

3: 25 percent / NH₃; NH₄Cl / H₂O / 5 h / Heating

With potassium hydroxide; ammonia; bromine; sodium hydrogencarbonate; ammonium chloride; In methanol; water;
DOI:10.1071/CH03202