trans-{(benzothiazole-2-thiolato)carbonylbis(triphenylphosphine)rhodium}

Base Information

• Chemical Name: trans-{(benzothiazole-2-thiolato)carbonylbis(triphenylphosphine)rhodium}
• CAS No.: 150724-84-8
• Molecular Formula: C₄₄H₃₄NOP₂RhS₂
• Molecular Weight: 821.745
• Mol file: 150724-84-8.mol

Synonyms:trans-{(benzothiazole-2-thiolato)carbonylbis(triphenylphosphine)rhodium}

Chemical Property of trans-{(benzothiazole-2-thiolato)carbonylbis(triphenylphosphine)rhodium}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-{(benzothiazole-2-thiolato)carbonylbis(triphenylphosphine)rhodium}

There total 4 articles about trans-{(benzothiazole-2-thiolato)carbonylbis(triphenylphosphine)rhodium} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + lithium benzothiazole-2-thiolate (66648-22-4) → trans-{(benzothiazole-2-thiolato)carbonylbis(triphenylphosphine)rhodium} (150724-84-8)

Guidance literature:

In tetrahydrofuran; under N2; addn. of starting complex to a soln. of thiolate in THF, stirring for 30 min; evapn. undwer vac., addn. of methanol, filtration, washed, dried under vacuum;

DOI:10.1016/0022-328X(93)80403-X

Reference yield: 80.0%

{Rh(benzothiazole-2-thiolate)(CO)(triphenylphosphine)}2 (122658-53-1) → trans-{(benzothiazole-2-thiolato)carbonylbis(triphenylphosphine)rhodium} (150724-84-8)

Guidance literature:

With P(C₆H₅)3; In dichloromethane; under N2; PPh3 is added to a soln. of starting complex; soln. is concd., addn. of hexane, filtration, washed, dried under vac., elem. anal.;

DOI:10.1016/0022-328X(93)80403-X

Reference yield:

{di-μ-(benzothiazole-2-thiolato-S,N)-bis{dicarbonylrhodium(I)} (122658-52-0) → trans-{(benzothiazole-2-thiolato)carbonylbis(triphenylphosphine)rhodium} (150724-84-8)

Guidance literature:

Multi-step reaction with 3 steps

1: P(C₆H₅)3 / dichloromethane

2: dichloromethane

3: P(C₆H₅)3 / dichloromethane

With P(C₆H₅)3; In dichloromethane;

DOI:10.1016/0022-328X(93)80403-X

upstream raw materials:

{Rh(benzothiazole-2-thiolate)(CO)(triphenylphosphine)}2

chlorocarbonylbis(triphenylphosphine)rhodium(I)

lithium benzothiazole-2-thiolate

{di-μ-(benzothiazole-2-thiolato-S,N)-bis{dicarbonylrhodium(I)}