Tris[4-(heptadecafluorooctyl)phenyl]phosphine

Base Information

Chemical Name:Tris[4-(heptadecafluorooctyl)phenyl]phosphine
CAS No.:284472-92-0
Molecular Formula:C₄₂H₁₂F₅₁P
Molecular Weight:1516.45
Hs Code.:
European Community (EC) Number:622-446-0
DSSTox Substance ID:DTXSID00395302
Nikkaji Number:J1.315.223C
Wikidata:Q82195304
Mol file:284472-92-0.mol

Synonyms:Tris[4-(heptadecafluorooctyl)phenyl]phosphine;284472-92-0;Tris[4-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]phosphane;Tris(4-(perfluorooctyl)phenyl)phosphane;DTXSID00395302;RTNPUWLBWXIECX-UHFFFAOYSA-N;J-017079;Tris[4-(heptadecafluorooctyl)phenyl]phosphine, >=85%

Suppliers and Price of Tris[4-(heptadecafluorooctyl)phenyl]phosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Tris[4-(heptadecafluorooctyl)phenyl]phosphine ≥85%
1g-f
$ 604.00

American Custom Chemicals Corporation
TRIS[4-(HEPTADECAFLUOROOCTYL)PHENYL]PHOSPHINE 95.00%
1G
$ 1308.56

Total 4 raw suppliers

Chemical Property of Tris[4-(heptadecafluorooctyl)phenyl]phosphine

Chemical Property:

Vapor Pressure:1.15E-12mmHg at 25°C
Melting Point:53-59 °C
Boiling Point:575.9°C at 760 mmHg
Flash Point:110 °C
PSA：13.59000
LogP:19.84250
XLogP3:21.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:51
Rotatable Bond Count:24
Exact Mass:1515.9862236
Heavy Atom Count:94
Complexity:2330

Purity/Quality:

99% ^*data from raw suppliers

Tris[4-(heptadecafluorooctyl)phenyl]phosphine ≥85% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=CC=C1C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)P(C2=CC=C(C=C2)C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)C3=CC=C(C=C3)C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
Uses Reactant for synthesis of:Triarylphosphine selenidesPerfluoroalkylated arylphosphinesReactant for:Suzuki couplingStille coupling

Technology Process of Tris[4-(heptadecafluorooctyl)phenyl]phosphine

There total 7 articles about Tris[4-(heptadecafluorooctyl)phenyl]phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: tris(4-perfluorooctylphenyl)phosphine oxide

: 284472-92-0
tris(4-heptadecafluoro-n-octylphenyl)phosphine

Guidance literature:: With trichlorosilane; triethylamine; In toluene; for 6h; Heating;
DOI:10.1016/S0040-4039(00)00445-7

Reference yield: 25.0%

: 206560-77-2
1-bromo-4-(heptadecafluorooctyl)benzene

: 284472-92-0
tris(4-heptadecafluoro-n-octylphenyl)phosphine

Guidance literature:: 1-bromo-4-(heptadecafluorooctyl)benzene; With n-butyllithium; In diethyl ether; hexane; at -78 ℃;

With phosphorus trichloride; In diethyl ether; hexane; at -78 - 20 ℃;

Reference yield:

: 507-63-1
1-iodoheptadecafluorooctane

: 284472-92-0
tris(4-heptadecafluoro-n-octylphenyl)phosphine

Guidance literature:: Multi-step reaction with 3 steps

1.1: Cu / dimethylformamide / 120 °C

2.1: tBuONO; CuBr₂ / acetonitrile / -5 - 20 °C

3.1: nBuLi / diethyl ether; hexane / -78 °C

3.2: 25 percent / PCl₃ / diethyl ether; hexane / -78 - 20 °C

With n-butyllithium; tert.-butylnitrite; copper; copper(ll) bromide; In diethyl ether; hexane; N,N-dimethyl-formamide; acetonitrile;