3,5-Dinitro-benzoic acid (S)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester

Base Information

Chemical Name:3,5-Dinitro-benzoic acid (S)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester
CAS No.:120093-52-9
Molecular Formula:C₁₈H₂₂N₂O₇
Molecular Weight:378.382
Hs Code.:

Synonyms:3,5-Dinitro-benzoic acid (S)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3,5-Dinitro-benzoic acid (S)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester

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Technology Process of 3,5-Dinitro-benzoic acid (S)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester

There total 7 articles about 3,5-Dinitro-benzoic acid (S)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 120093-51-8,120093-53-0
[2-((R)-1,5-Dimethyl-hex-4-enyl)-oxiranyl]-methanol

: 99-33-2
3,5-dinitrobenoyl chloride

: 120093-54-1
3,5-Dinitro-benzoic acid (R)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester

: 120093-52-9
3,5-Dinitro-benzoic acid (S)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester

Guidance literature:: With pyridine; for 4h;
DOI:10.1021/jo00034a017

Reference yield:

: 2385-77-5
(R)-Citronellal

: 120093-52-9
3,5-Dinitro-benzoic acid (S)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: LDA / tetrahydrofuran

2: methanol

3: aq. NaHCO₃ / CH₂Cl₂

4: 95 percent / NaBH₄, CeCl₃ / methanol

5: 69 percent / cumene hydroperoxide / diisopropyl (-)-tartrate, Ti(i-OPr)4

6: DMAP / pyridine

With dmap; sodium tetrahydroborate; cerium(III) chloride; Cumene hydroperoxide; sodium hydrogencarbonate; lithium diisopropyl amide; titanium(IV) isopropylate; (-)-diisopropyl tartrate; In tetrahydrofuran; pyridine; methanol; dichloromethane;
DOI:10.1016/S0040-4039(00)86693-9

Reference yield:

: 18951-85-4,57030-77-0
(R)-citronellic acid

: 120093-52-9
3,5-Dinitro-benzoic acid (S)-2-((R)-1,5-dimethyl-hex-4-enyl)-oxiranylmethyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 97 percent / LiAlH₄ / diethyl ether

2: 70 percent / pyridinium chlorochromate / CH₂Cl₂

3: LDA / tetrahydrofuran

4: methanol

5: aq. NaHCO₃ / CH₂Cl₂

6: 95 percent / NaBH₄, CeCl₃ / methanol

7: 69 percent / cumene hydroperoxide / diisopropyl (-)-tartrate, Ti(i-OPr)4

8: DMAP / pyridine

With dmap; sodium tetrahydroborate; lithium aluminium tetrahydride; cerium(III) chloride; Cumene hydroperoxide; sodium hydrogencarbonate; pyridinium chlorochromate; lithium diisopropyl amide; titanium(IV) isopropylate; (-)-diisopropyl tartrate; In tetrahydrofuran; pyridine; methanol; diethyl ether; dichloromethane;
DOI:10.1016/S0040-4039(00)86693-9