Benzoic acid (2E,4Z,7Z)-(R)-1-[(Z)-(S)-1-(2-chloro-acetoxy)-oct-2-enyl]-11-methoxycarbonyl-undeca-2,4,7-trienyl ester

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Chemical Name:Benzoic acid (2E,4Z,7Z)-(R)-1-[(Z)-(S)-1-(2-chloro-acetoxy)-oct-2-enyl]-11-methoxycarbonyl-undeca-2,4,7-trienyl ester
CAS No.:131938-80-2
Molecular Formula:C₃₀H₃₉ClO₆
Molecular Weight:531.089
Hs Code.:

Synonyms:Benzoic acid (2E,4Z,7Z)-(R)-1-[(Z)-(S)-1-(2-chloro-acetoxy)-oct-2-enyl]-11-methoxycarbonyl-undeca-2,4,7-trienyl ester

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Chemical Property of Benzoic acid (2E,4Z,7Z)-(R)-1-[(Z)-(S)-1-(2-chloro-acetoxy)-oct-2-enyl]-11-methoxycarbonyl-undeca-2,4,7-trienyl ester

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Technology Process of Benzoic acid (2E,4Z,7Z)-(R)-1-[(Z)-(S)-1-(2-chloro-acetoxy)-oct-2-enyl]-11-methoxycarbonyl-undeca-2,4,7-trienyl ester

There total 7 articles about Benzoic acid (2E,4Z,7Z)-(R)-1-[(Z)-(S)-1-(2-chloro-acetoxy)-oct-2-enyl]-11-methoxycarbonyl-undeca-2,4,7-trienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 131938-77-7
Benzoic acid (2E,4Z,7Z)-(R)-1-((Z)-(R)-1-hydroxy-oct-2-enyl)-11-methoxycarbonyl-undeca-2,4,7-trienyl ester

: 79-11-8
chloroacetic acid

: 131938-80-2
Benzoic acid (2E,4Z,7Z)-(R)-1-[(Z)-(S)-1-(2-chloro-acetoxy)-oct-2-enyl]-11-methoxycarbonyl-undeca-2,4,7-trienyl ester

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 0.166667h; Ambient temperature;
DOI:10.1016/S0040-4039(00)89001-2

Reference yield:

: C₄₀H₃₆O₇

: 131938-80-2
Benzoic acid (2E,4Z,7Z)-(R)-1-[(Z)-(S)-1-(2-chloro-acetoxy)-oct-2-enyl]-11-methoxycarbonyl-undeca-2,4,7-trienyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: ZnBr₂ / CH₂Cl₂; methanol / 1 h / 24 °C

2: pyridinium dichromate / CH₂Cl₂ / 1 h / 24 °C

3: tetrahydrofuran; toluene / 0.5 h / -78 °C

4: NaI, Me₃SiCl / acetonitrile / 1 h / 0 °C

5: tetrahydrofuran; hexamethylphosphoric acid triamide / 1 h / 40 °C

6: 76 percent / diethyl azodicarboxylate, Ph₃P / tetrahydrofuran / 0.17 h / Ambient temperature

With dipyridinium dichromate; chloro-trimethyl-silane; triphenylphosphine; sodium iodide; zinc dibromide; diethylazodicarboxylate; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; toluene; acetonitrile;
DOI:10.1016/S0040-4039(00)89001-2

Reference yield:

: 131938-75-5
C₂₁H₂₀O₇

: 131938-80-2
Benzoic acid (2E,4Z,7Z)-(R)-1-[(Z)-(S)-1-(2-chloro-acetoxy)-oct-2-enyl]-11-methoxycarbonyl-undeca-2,4,7-trienyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: tetrahydrofuran; toluene / 0.5 h / -78 °C

2: NaI, Me₃SiCl / acetonitrile / 1 h / 0 °C

3: tetrahydrofuran; hexamethylphosphoric acid triamide / 1 h / 40 °C

4: 76 percent / diethyl azodicarboxylate, Ph₃P / tetrahydrofuran / 0.17 h / Ambient temperature

With chloro-trimethyl-silane; triphenylphosphine; sodium iodide; diethylazodicarboxylate; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; toluene; acetonitrile;
DOI:10.1016/S0040-4039(00)89001-2