(η5-1-C(CH2)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

Base Information

Chemical Name:(η5-1-C(CH2)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese
CAS No.:1012785-80-6
Molecular Formula:C₂₂H₁₇MnO₄S
Molecular Weight:432.379
Hs Code.:

Synonyms:(η5-1-C(CH2)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

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Chemical Property of (η5-1-C(CH2)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

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Technology Process of (η5-1-C(CH2)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

There total 1 articles about (η5-1-C(CH2)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 1012785-86-2,1013331-87-7
(η5-1-C(OH)(Me)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

: 1012785-82-8
OC₆H₅(C₆H₅)C(CH₃)C₄H₃S

: 1012785-80-6
(η5-1-C(CH2)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

Guidance literature:: With HBF₄*OMe₂; In dichloromethane; under N2; HBF4*OMe2 added dropwise at -35°C to soln. of Mn complex in CH2Cl2; stirred at -35°C for 1.5 h; H2O added at room temp.; aq. phase extd. with Et2O; org. phase washed (H2O, satd. aq. NaCl); dried (MgSO4); solvent removed under reduced pressure; dried in vac.; purified by column chromy. (silica gel, petroleum ether-Et2O); elem. anal.;
DOI:10.1021/om7010672