(2R,3R)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol

Base Information

Chemical Name:(2R,3R)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol
CAS No.:140479-39-6
Molecular Formula:C₃₁H₄₀O₄Si
Molecular Weight:504.742
Hs Code.:

Synonyms:(2R,3R)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3R)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol

Chemical Property:

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Technology Process of (2R,3R)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol

There total 1 articles about (2R,3R)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 24850-33-7
allyltributylstanane

: 138436-29-0
(R)-2-Benzyloxymethoxymethyl-3-(tert-butyl-diphenyl-silanyloxy)-propionaldehyde

: 140479-39-6
(2R,3R)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol

: 140479-46-5
(2R,3S)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol

Guidance literature:: With magnesium bromide; In dichloromethane; Yield given. Yields of byproduct given; -78 to 0 deg C;
DOI:10.1016/0040-4039(91)80449-G

Reference yield: 79.0%

: 140479-39-6
(2R,3R)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol

: 146512-60-9
(2S,3R)-2-(((benzyloxy)methoxy)methyl)hex-5-ene-1,3-diol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 3h; Ambient temperature;
DOI:10.1021/jo00058a036

Reference yield:

: 140479-39-6
(2R,3R)-2-Benzyloxymethoxymethyl-1-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-3-ol

: 140479-51-2
(4R,5R)-cis-4-allyl-5-(((benzyloxy)methoxy)methyl)-2,2-dimethyl-1,3-dioxane

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / n-Bu₄NF*3H₂O / tetrahydrofuran / 3 h / Ambient temperature

2: 79 percent / p-toluenesulfonic acid hydrate / CH₂Cl₂; tetrahydrofuran / 0.17 h / Ambient temperature

With tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00058a036