2-(4-nitrophenyl)-4-(4-methoxyphenyl)-3-methyl-1,3-oxazolium-5-olate

Base Information

• Chemical Name: 2-(4-nitrophenyl)-4-(4-methoxyphenyl)-3-methyl-1,3-oxazolium-5-olate
• CAS No.: 28609-01-0
• Molecular Formula: C₁₇H₁₄N₂O₅
• Molecular Weight: 326.309
• Mol file: 28609-01-0.mol

Synonyms:2-(4-nitrophenyl)-4-(4-methoxyphenyl)-3-methyl-1,3-oxazolium-5-olate

Chemical Property of 2-(4-nitrophenyl)-4-(4-methoxyphenyl)-3-methyl-1,3-oxazolium-5-olate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 2-(4-nitrophenyl)-4-(4-methoxyphenyl)-3-methyl-1,3-oxazolium-5-olate

There total 1 articles about 2-(4-nitrophenyl)-4-(4-methoxyphenyl)-3-methyl-1,3-oxazolium-5-olate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

N-(4-nitrobenzoyl)-N-methyl-C-(4-methoxyphenyl)glycine (28544-49-2) → 2-(4-nitrophenyl)-4-(4-methoxyphenyl)-3-methyl-1,3-oxazolium-5-olate (28609-01-0)

Guidance literature:

With acetic anhydride; at 55 ℃; Inert atmosphere;

DOI:10.1039/c0ob00416b

Reference yield: 39.0%

2-(4-nitrophenyl)-4-(4-methoxyphenyl)-3-methyl-1,3-oxazolium-5-olate (28609-01-0) + p-nitrophenyl isothiocyanate (2131-61-5) → 1-methyl-5-(4-methoxyphenyl)-2,3-bis(4-nitrophenyl)-1,3-diazolium-4-thiolate (1602766-91-5) + 1-methyl-2-(4-methoxyphenyl)-3,5-bis(4-nitrophenyl)-1,3-diazolium-4-thiolate (1602766-93-7)

Guidance literature:

In N,N-dimethyl-formamide; at 140 ℃; for 0.1h; Microwave irradiation;

DOI:10.1021/jo500349g

Reference yield: 34.0%

carbon disulfide (75-15-0,12122-00-8) + 2-(4-nitrophenyl)-4-(4-methoxyphenyl)-3-methyl-1,3-oxazolium-5-olate (28609-01-0) → 4-(4-methoxyphenyl)-3-methyl-2-(4-nitrophenyl)-1,3-thiazolium-5-thiolate (1260403-47-1) + 2-(4-methoxyphenyl)-3-methyl-4-(4-nitrophenyl)-1,3-thiazolium-5-thiolate (1260403-48-2)

Guidance literature:

In N,N-dimethyl-formamide; for 4h; Reflux;

DOI:10.1039/c0ob00416b

upstream raw materials:

N-(4-nitrobenzoyl)-N-methyl-C-(4-methoxyphenyl)glycine

Downstream raw materials:

4-(4-methoxyphenyl)-3-methyl-2-(4-nitrophenyl)-1,3-thiazolium-5-thiolate

2-(4-methoxyphenyl)-3-methyl-4-(4-nitrophenyl)-1,3-thiazolium-5-thiolate

1-methyl-5-(4-methoxyphenyl)-2-(4-nitrophenyl)-3-phenyl-1,3-diazolium-4-thiolate

1-methyl-2-(4-methoxyphenyl)-5-(4-nitrophenyl)-3-phenyl-1,3-diazolium-4-thiolate