α,α,α-trideuterioacetophenone tosylhydrazone

Base Information

• Chemical Name: α,α,α-trideuterioacetophenone tosylhydrazone
• CAS No.: 105930-65-2
• Molecular Formula: C₁₅H₁₆N₂O₂S
• Molecular Weight: 291.346
• Mol file: 105930-65-2.mol

Synonyms:α,α,α-trideuterioacetophenone tosylhydrazone

Chemical Property of α,α,α-trideuterioacetophenone tosylhydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of α,α,α-trideuterioacetophenone tosylhydrazone

There total 1 articles about α,α,α-trideuterioacetophenone tosylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Acetophenone-methyl-d3 (17537-31-4) + toluene-4-sulfonic acid hydrazide (1576-35-8) → α,α,α-trideuterioacetophenone tosylhydrazone (105930-65-2)

Guidance literature:

DOI:10.1021/ja00237a008

Reference yield: 76.0%

norbornene (498-66-8) + α,α,α-trideuterioacetophenone tosylhydrazone (105930-65-2) + 1-Bromo-2-phenylacetylene (932-87-6) → 3-phenyl-3-(4-(1-phenylvinyl-2,2-d2)bicyclo[3.2.1]oct-2-en-3-yl)tricyclo[3.2.1.02,4]octane

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; trifuran-2-yl-phosphane; lithium tert-butoxide; In toluene; at 100 ℃; for 4h; diastereoselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1002/asia.201701241

Reference yield: 68.0%

N,N-Dimethylacrylamide (2680-03-7,68761-83-1) + α,α,α-trideuterioacetophenone tosylhydrazone (105930-65-2) → C13H14(2)H3NO

Guidance literature:

With palladium diacetate; lithium tert-butoxide; In water; acetonitrile; at 90 ℃; for 14h; stereoselective reaction; Inert atmosphere;

DOI:10.1002/chem.201202051

upstream raw materials:

Acetophenone-methyl-d3

toluene-4-sulfonic acid hydrazide

Downstream raw materials:

styrene-α,α,β-d3

2,2,2-trideuterio-1-phenyldiazomethane

4-phenyl-2-quinolinone