5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine

Base Information

Chemical Name:5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine
CAS No.:616229-91-5
Molecular Formula:C₈₅H₁₀₁I₂N₃O₂
Molecular Weight:1450.56
Hs Code.:

Synonyms:5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine

Suppliers and Price of 5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine

There total 5 articles about 5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 162715-91-5
1,4-dihexyl-2,5-diiodobenzene

: 569672-59-9
5,5'-bis{[3-ethynyl-5-(hexoxymethyl)phenyl]ethynyl}-2,2':6',2''-terpyridine

: 616229-91-5
5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine

Guidance literature:: With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In toluene; at 60 ℃; for 72h;
DOI:10.1021/ja034029p

Reference yield:

: 73290-22-9
2-bromo-5-iodo-pyridine

: 616229-91-5
5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / Et₃N; Pd[P(Ph₃)]4; CuI / 72 h / 60 °C

2: 55 percent / Pd[P(Ph₃)]4 / toluene / 36 h / Heating

3: 75 percent / Bu₄NF*3H₂O / tetrahydrofuran

4: 51 percent / Et₃N; Pd[P(Ph₃)]4; CuI / toluene / 72 h / 60 °C

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran; toluene; 1: Sonogashira cross-coupling / 4: Sonogashira cross-coupling;
DOI:10.1021/ja034029p

Reference yield:

: 296761-60-9
(2-(3-ethynyl-5-((hexyloxy)methyl)phenyl)ethynyl)triisopropylsilane

: 616229-91-5
5,5'-bis({3-hexoxymethyl-5-[(2,5-dihexyl-4-iodophenyl)ethynyl]phenyl}ethynyl)-2,2':6',2''-terpyridine

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / Et₃N; Pd[P(Ph₃)]4; CuI / 72 h / 60 °C

2: 55 percent / Pd[P(Ph₃)]4 / toluene / 36 h / Heating

3: 75 percent / Bu₄NF*3H₂O / tetrahydrofuran

4: 51 percent / Et₃N; Pd[P(Ph₃)]4; CuI / toluene / 72 h / 60 °C

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran; toluene; 1: Sonogashira cross-coupling / 4: Sonogashira cross-coupling;
DOI:10.1021/ja034029p