3-<(tert-butyldimethylsilyl)oxy>-1-(phenylsulfonyl)-2-(2'-propenyl)-1,3-cyclohexadiene

Base Information

Chemical Name:3-<(tert-butyldimethylsilyl)oxy>-1-(phenylsulfonyl)-2-(2'-propenyl)-1,3-cyclohexadiene
CAS No.:115961-01-8
Molecular Formula:C₂₁H₃₀O₃SSi
Molecular Weight:390.619
Hs Code.:

Synonyms:3-<(tert-butyldimethylsilyl)oxy>-1-(phenylsulfonyl)-2-(2'-propenyl)-1,3-cyclohexadiene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-<(tert-butyldimethylsilyl)oxy>-1-(phenylsulfonyl)-2-(2'-propenyl)-1,3-cyclohexadiene

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Technology Process of 3-<(tert-butyldimethylsilyl)oxy>-1-(phenylsulfonyl)-2-(2'-propenyl)-1,3-cyclohexadiene

There total 1 articles about 3-<(tert-butyldimethylsilyl)oxy>-1-(phenylsulfonyl)-2-(2'-propenyl)-1,3-cyclohexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 105728-95-8
3-(phenylsulfonyl)-2-(2'-propenyl)cyclohex-2-enone

: 115961-01-8
3-<(tert-butyldimethylsilyl)oxy>-1-(phenylsulfonyl)-2-(2'-propenyl)-1,3-cyclohexadiene

Guidance literature:: With triethylamine; In dichloromethane; at 25 ℃; for 1h;
DOI:10.1021/jo00379a038

Reference yield:

: 115961-01-8
3-<(tert-butyldimethylsilyl)oxy>-1-(phenylsulfonyl)-2-(2'-propenyl)-1,3-cyclohexadiene

: 105728-96-9
6-<(tert-butyldimethylsilyl)oxy>-3-(phenylsulfonyl)-2-(2'-propenyl)cyclohex-2-enone

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 - 25 ℃; for 2h; Yield given;
DOI:10.1021/jo00379a038

Reference yield:

: 115961-01-8
3-<(tert-butyldimethylsilyl)oxy>-1-(phenylsulfonyl)-2-(2'-propenyl)-1,3-cyclohexadiene

: 105728-97-0
cis-4-<(tert-butyldimethylsilyl)oxy>-3-hydroxy-1-(phenylsulfonyl)-2-(2'-propenyl)cyclohexene

Guidance literature:: Multi-step reaction with 2 steps

1: m-chloroperbenzoic acid (MCPBA) / CH₂Cl₂ / 2 h / -78 - 25 °C

2: 95 percent / CeCl₃, NaBH₄ / CH₂Cl₂; methanol / 0.5 h / -20 - 0 °C

With sodium tetrahydroborate; cerium(III) chloride; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane;
DOI:10.1021/jo00379a038