biscarbonyl (O,O′-(N-nitroso-N-oxido-(2-tolyl)amine))rhodium(I)

Base Information

• Chemical Name: biscarbonyl (O,O′-(N-nitroso-N-oxido-(2-tolyl)amine))rhodium(I)
• CAS No.: 1418212-17-5
• Molecular Formula: C₉H₇N₂O₄Rh
• Molecular Weight: 310.071
• Mol file: 1418212-17-5.mol

Synonyms:biscarbonyl (O,O′-(N-nitroso-N-oxido-(2-tolyl)amine))rhodium(I)

Chemical Property of biscarbonyl (O,O′-(N-nitroso-N-oxido-(2-tolyl)amine))rhodium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of biscarbonyl (O,O′-(N-nitroso-N-oxido-(2-tolyl)amine))rhodium(I)

There total 1 articles about biscarbonyl (O,O′-(N-nitroso-N-oxido-(2-tolyl)amine))rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

di(rhodium)tetracarbonyl dichloride + 2-methylcupferrate → biscarbonyl (O,O′-(N-nitroso-N-oxido-(2-tolyl)amine))rhodium(I) (1418212-17-5)

Guidance literature:

In N,N-dimethyl-formamide;

DOI:10.1016/j.jorganchem.2012.12.005

Reference yield:

biscarbonyl (O,O′-(N-nitroso-N-oxido-(2-tolyl)amine))rhodium(I) (1418212-17-5) + Tri(p-tolyl)phosphine (1038-95-5,218281-19-7) → carbonyl tris(4-tolyl)phosphine (O,O′-(N-nitroso-N-oxido-(2-tolyl)-amine))rhodium(I) (1418212-19-7,1418572-89-0) + carbonyl tris(4-tolyl)phosphine (O,O′-(N-nitroso-N-oxido-(2-tolyl)-amine))rhodium(I) (1418212-19-7,1418572-89-0)

Guidance literature:

In acetone; Overall yield = 78 %;

DOI:10.1016/j.jorganchem.2012.12.005

Reference yield:

biscarbonyl (O,O′-(N-nitroso-N-oxido-(2-tolyl)amine))rhodium(I) (1418212-17-5) + P(p-CH3OC6H4)3 (855-38-9) → carbonyl tris(4-methoxyphenyl)phosphine (O,O′-(N-nitroso-N-oxido-(2-tolyl)-amine))rhodium(I) (1418212-20-0,1418572-93-6) + carbonyl tris(4-methoxyphenyl)phosphine (O,O′-(N-nitroso-N-oxido-(2-tolyl)-amine))rhodium(I) (1418212-20-0,1418572-93-6)

Guidance literature:

In acetone; Overall yield = 93 %;

DOI:10.1016/j.jorganchem.2012.12.005

Downstream raw materials:

carbonyl tris(4-tolyl)phosphine (O,O′-(N-nitroso-N-oxido-(2-tolyl)-amine))rhodium(I)

carbonyl tris(4-tolyl)phosphine (O,O′-(N-nitroso-N-oxido-(2-tolyl)-amine))rhodium(I)

carbonyl tris(4-methoxyphenyl)phosphine (O,O′-(N-nitroso-N-oxido-(2-tolyl)-amine))rhodium(I)

carbonyl tris(4-methoxyphenyl)phosphine (O,O′-(N-nitroso-N-oxido-(2-tolyl)-amine))rhodium(I)