methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside

Base Information

Chemical Name:methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside
CAS No.:1350309-54-4
Molecular Formula:C₂₅H₂₆O₅S
Molecular Weight:438.544
Hs Code.:

Synonyms:methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside

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Chemical Property of methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside

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Technology Process of methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside

There total 4 articles about methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1350309-53-3
methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-3-O-triisopropylsilyl-α-D-mannopyranoside

: 1350309-54-4
methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 - 20 ℃; for 18h; Inert atmosphere;
DOI:10.1021/ja208528c

Reference yield:

: 1350309-52-2
methyl 4,6-O-benzylidene-1-thio-3-O-triisopropylsilyl-α-D-mannopyranoside

: 1350309-54-4
methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride / N,N-dimethyl-formamide / 3 h / 0 - 20 °C / Inert atmosphere

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 18 h / 0 - 20 °C / Inert atmosphere

With tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/ja208528c

Reference yield:

: 939-26-4
2-bromomethylnaphthyl bromide

: 1350309-54-4
methyl 4,6-O-benzylidene-2-O-(2-naphthylmethyl)-1-thio-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride / N,N-dimethyl-formamide / 3 h / 0 - 20 °C / Inert atmosphere

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 18 h / 0 - 20 °C / Inert atmosphere

With tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/ja208528c