C₃₄H₄₅ClO₄SSi

Base Information

• Chemical Name: C₃₄H₄₅ClO₄SSi
• CAS No.: 934747-52-1
• Molecular Formula: C₃₄H₄₅ClO₄SSi
• Molecular Weight: 613.333
• Mol file: 934747-52-1.mol

Synonyms:C₃₄H₄₅ClO₄SSi

Chemical Property of C₃₄H₄₅ClO₄SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₄H₄₅ClO₄SSi

There total 15 articles about C₃₄H₄₅ClO₄SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C34H46O4SSi (934747-66-7) → C34H45ClO4SSi (934747-52-1)

Guidance literature:

With N-chloro-succinimide; In tetrachloromethane; dichloromethane; at 20 ℃;

DOI:10.1016/j.tetlet.2007.01.102

Reference yield:

C23H27NO7Se → C34H45ClO4SSi (934747-52-1)

Guidance literature:

Multi-step reaction with 12 steps

1.1: H₂O₂ / tetrahydrofuran; H₂O / 0 - 20 °C

2.1: dimethylformamide; tetrahydrofuran / 0 °C

3.1: 96 percent / (PCy₃)2Cl₂Ru=CHPh / CH₂Cl₂ / 20 °C

4.1: TFA / tetrahydrofuran / 20 °C

4.2: 98 percent / imidazole / dimethylformamide / 20 °C

5.1: m-CPBA; NaHCO₃ / CH₂Cl₂ / 0 - 20 °C

6.1: LiAlH₄ / diethyl ether / -20 °C

7.1: TBAI; NaH / tetrahydrofuran; dimethylformamide / 20 °C

7.2: 51 percent / CSA / methanol; tetrahydrofuran / 0 °C

8.1: 95 percent / iodine; PPh₃; imidazole / tetrahydrofuran / 20 °C

9.1: 90 percent / dimethylsulfoxide / 45 °C

10.1: DIBAL-H / CH₂Cl₂ / -95 °C

10.2: 83 percent / NaBH₄ / CH₂Cl₂; methanol / -20 - 20 °C

11.1: 95 percent / nBu₃P; pyridine / 20 °C

12.1: NCS / CH₂Cl₂; CCl₄ / 20 °C

With pyridine; 1H-imidazole; N-chloro-succinimide; lithium aluminium tetrahydride; tributylphosphine; dihydrogen peroxide; iodine; tetra-(n-butyl)ammonium iodide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; trifluoroacetic acid; Grubbs catalyst first generation; In tetrahydrofuran; tetrachloromethane; diethyl ether; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide;

DOI:10.1016/j.tetlet.2007.01.102

Reference yield:

C17H22O5 → C34H45ClO4SSi (934747-52-1)

Guidance literature:

Multi-step reaction with 11 steps

1.1: dimethylformamide; tetrahydrofuran / 0 °C

2.1: 96 percent / (PCy₃)2Cl₂Ru=CHPh / CH₂Cl₂ / 20 °C

3.1: TFA / tetrahydrofuran / 20 °C

3.2: 98 percent / imidazole / dimethylformamide / 20 °C

4.1: m-CPBA; NaHCO₃ / CH₂Cl₂ / 0 - 20 °C

5.1: LiAlH₄ / diethyl ether / -20 °C

6.1: TBAI; NaH / tetrahydrofuran; dimethylformamide / 20 °C

6.2: 51 percent / CSA / methanol; tetrahydrofuran / 0 °C

7.1: 95 percent / iodine; PPh₃; imidazole / tetrahydrofuran / 20 °C

8.1: 90 percent / dimethylsulfoxide / 45 °C

9.1: DIBAL-H / CH₂Cl₂ / -95 °C

9.2: 83 percent / NaBH₄ / CH₂Cl₂; methanol / -20 - 20 °C

10.1: 95 percent / nBu₃P; pyridine / 20 °C

11.1: NCS / CH₂Cl₂; CCl₄ / 20 °C

With pyridine; 1H-imidazole; N-chloro-succinimide; lithium aluminium tetrahydride; tributylphosphine; iodine; tetra-(n-butyl)ammonium iodide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; trifluoroacetic acid; Grubbs catalyst first generation; In tetrahydrofuran; tetrachloromethane; diethyl ether; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;

DOI:10.1016/j.tetlet.2007.01.102

upstream raw materials:

C₃₄H₄₆O₄SSi

C₂₀H₂₆O₅

C₁₈H₂₂O₅

C₂₂H₄₄O₄Si₂