Tetra-dithiobenzoato-di-μ-thiodinickel

Base Information

• Chemical Name: Tetra-dithiobenzoato-di-μ-thiodinickel
• CAS No.: 17442-68-1
• Molecular Formula: C₂₈H₂₀Ni₂S₁₀
• Molecular Weight: 794.507
• Mol file: 17442-68-1.mol

Synonyms:Tetra-dithiobenzoato-di-μ-thiodinickel

Chemical Property of Tetra-dithiobenzoato-di-μ-thiodinickel

Chemical Property:

Purity/Quality:

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Technology Process of Tetra-dithiobenzoato-di-μ-thiodinickel

There total 5 articles about Tetra-dithiobenzoato-di-μ-thiodinickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium hydrogen sulfide + Ni dithiobenzoate → C6H5CS2(1-) (41003-56-9) + Tetra-dithiobenzoato-di-μ-thiodinickel (17442-68-1) + tetracarbonyl nickel (13463-39-3,71564-36-8)

Guidance literature:

With carbon monoxide; In ethanol; byproducts: H2S; Na-polysulfide in alc., (Ni(C7H5S2)2) in CS2; CO passed into the reaction mixt.;

Reference yield:

nickel(II) chloride hexahydrate + tetraethylammonium chloride monohydrate (68696-18-4) + phosphorous (V) sulfide → Tetra-dithiobenzoato-di-μ-thiodinickel (17442-68-1)

Guidance literature:

With benzoic acid; byproducts: HCl; melting the reactants; extn. with benzene, evapn., recrystn from THF/H2O mixture, then from benzene;

DOI:10.1021/ja00983a045

Reference yield:

Ni dithiobenzoate → Tetra-dithiobenzoato-di-μ-thiodinickel (17442-68-1)

Guidance literature:

With Na-polysulfide; In carbon disulfide; ethanol; Na-polysulfide in alc., (Ni(C7H5S2)2) in CS2;

upstream raw materials:

thiobenzoic acid

tetraethylammonium chloride monohydrate

Downstream raw materials:

triphenylphosphine sulfide