nido-6-iridadecaborane

Base Information

Chemical Name:nido-6-iridadecaborane
CAS No.:82106-45-4
Molecular Formula:C₃₆H₄₄B₉IrP₂
Molecular Weight:828.212
Hs Code.:

Synonyms:nido-6-iridadecaborane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of nido-6-iridadecaborane

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Technology Process of nido-6-iridadecaborane

There total 2 articles about nido-6-iridadecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.4%

: 17702-41-9
nido-decaborane

: 16070-58-9
tris(triphenylphosphine)chloroiridium

: 82106-45-4
nido-6-iridadecaborane

Guidance literature:: nido-decaborane; With potassium hydroxide; In methanol; Inert atmosphere;

tris(triphenylphosphine)chloroiridium; In diethyl ether; Inert atmosphere;
DOI:10.1039/d1dt02971a

Reference yield: 81.0%

: 16070-58-9
tris(triphenylphosphine)chloroiridium

: NEt₄ arachno-nonaborate

: 82106-45-4
nido-6-iridadecaborane

Guidance literature:: In dichloromethane; byproducts: isonido-iridadecaborane; Ir-complex is stirred in CH2Cl2 with nonaborate for 45 min (under N2); mixt. is reduced in volume on a rotary evaporator, preparative TLC with CH2Cl2-pentane, 1. fraction gives product and 2. fraction gives isonido-compd.;
DOI:10.1039/DT9900001441

Reference yield: 42.0%

: 593-75-9,685498-28-6
methyl isocyanate

: 82106-45-4
nido-6-iridadecaborane

: [6,6,6,6-(MeNC)2(PPh₃)H-arachno-6-IrB₉H₁₁-9-(CNMe)]

: [6,6,6,6-(MeNC)2(PPh₃)H-arachno-6-IrB₉H₁₁-9-(PPh₃)]

Guidance literature:: In dichloromethane; under N2 atm. soln. MeNC in CH2Cl2 was added to soln. (6,6,6-(PPh3)2H-nido-6-IrB9H13) in CH2Cl2 and heated to reflux temp. for 4.5 h; react. mixt. was cooled to room temp., volatiles were removed in vacuo, preparative TLC;
DOI:10.1016/j.jorganchem.2005.02.028