benzyl benzyl((R)-1-((4R,5S)-5-((S)-1-hydroxyallyl)-2,2-dimethyl-1,3-dioxolan-4-yl)allyl)carbamate

Base Information

Chemical Name:benzyl benzyl((R)-1-((4R,5S)-5-((S)-1-hydroxyallyl)-2,2-dimethyl-1,3-dioxolan-4-yl)allyl)carbamate
CAS No.:1429612-45-2
Molecular Formula:C₂₆H₃₁NO₅
Molecular Weight:437.536
Hs Code.:

Synonyms:benzyl benzyl((R)-1-((4R,5S)-5-((S)-1-hydroxyallyl)-2,2-dimethyl-1,3-dioxolan-4-yl)allyl)carbamate

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Chemical Property of benzyl benzyl((R)-1-((4R,5S)-5-((S)-1-hydroxyallyl)-2,2-dimethyl-1,3-dioxolan-4-yl)allyl)carbamate

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Technology Process of benzyl benzyl((R)-1-((4R,5S)-5-((S)-1-hydroxyallyl)-2,2-dimethyl-1,3-dioxolan-4-yl)allyl)carbamate

There total 5 articles about benzyl benzyl((R)-1-((4R,5S)-5-((S)-1-hydroxyallyl)-2,2-dimethyl-1,3-dioxolan-4-yl)allyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1429612-43-0
(S)-1-((4S,5R)-5-((R)-1-(benzylamino)allyl)-2,2-dimethyl-1,3-dioxolan-4-yl)prop-2-en-1-ol

: 501-53-1,94274-21-2
benzyl chloroformate

: 1429612-45-2
benzyl benzyl((R)-1-((4R,5S)-5-((S)-1-hydroxyallyl)-2,2-dimethyl-1,3-dioxolan-4-yl)allyl)carbamate

Guidance literature:: With sodium hydrogencarbonate; In methanol; at 0 - 20 ℃; for 2h;
DOI:10.1016/j.tetlet.2013.02.046

Reference yield:

: 141436-58-0,126113-84-6
(-)-(1R)-1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3]dioxolan-4-yl]ethane-1,2-diol

: 1429612-45-2
benzyl benzyl((R)-1-((4R,5S)-5-((S)-1-hydroxyallyl)-2,2-dimethyl-1,3-dioxolan-4-yl)allyl)carbamate

Guidance literature:: Multi-step reaction with 4 steps

1: sodium periodate / tetrahydrofuran; water / 2 h / 0 °C

2: sodium sulfate / methanol / 12 h / Molecular sieve; Reflux

3: tetrahydrofuran / 3 h / -78 °C

4: sodium hydrogencarbonate / methanol / 2 h / 0 - 20 °C

With sodium periodate; sodium hydrogencarbonate; sodium sulfate; In tetrahydrofuran; methanol; water;
DOI:10.1016/j.tetlet.2013.02.046

Reference yield:

: (3aS,6S,6aS)-2,2-dimethyl-6-vinyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol

: 1429612-45-2
benzyl benzyl((R)-1-((4R,5S)-5-((S)-1-hydroxyallyl)-2,2-dimethyl-1,3-dioxolan-4-yl)allyl)carbamate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium sulfate / methanol / 12 h / Molecular sieve; Reflux

2: tetrahydrofuran / 3 h / -78 °C

3: sodium hydrogencarbonate / methanol / 2 h / 0 - 20 °C

With sodium hydrogencarbonate; sodium sulfate; In tetrahydrofuran; methanol;
DOI:10.1016/j.tetlet.2013.02.046