3,5-O-benzylidene-6,7-dideoxy-9,11-O-ethylidene-1,2-O-isopropylidene-7-nitro-α-D-undeco-1,4-furanose

Base Information

Chemical Name:3,5-O-benzylidene-6,7-dideoxy-9,11-O-ethylidene-1,2-O-isopropylidene-7-nitro-α-D-undeco-1,4-furanose
CAS No.:78931-03-0
Molecular Formula:C₂₃H₃₁NO₁₁
Molecular Weight:497.499
Hs Code.:

Synonyms:3,5-O-benzylidene-6,7-dideoxy-9,11-O-ethylidene-1,2-O-isopropylidene-7-nitro-α-D-undeco-1,4-furanose

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Chemical Property of 3,5-O-benzylidene-6,7-dideoxy-9,11-O-ethylidene-1,2-O-isopropylidene-7-nitro-α-D-undeco-1,4-furanose

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Technology Process of 3,5-O-benzylidene-6,7-dideoxy-9,11-O-ethylidene-1,2-O-isopropylidene-7-nitro-α-D-undeco-1,4-furanose

There total 5 articles about 3,5-O-benzylidene-6,7-dideoxy-9,11-O-ethylidene-1,2-O-isopropylidene-7-nitro-α-D-undeco-1,4-furanose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

: 901783-93-5,315216-23-0
2,4-O-ethylidene-aldehydo-D-erythrose

: 78954-41-3
3,5-O-benzylidene-6,7-dideoxy-1,2-O-isopropylidene-7-nitro-α-D-gluco-hepto-1,4-furanose

: 78931-03-0
3,5-O-benzylidene-6,7-dideoxy-9,11-O-ethylidene-1,2-O-isopropylidene-7-nitro-α-D-undeco-1,4-furanose

Guidance literature:: With sodium methylate; In tetrahydrofuran; methanol; for 3h;
DOI:10.1246/bcsj.54.1830

Reference yield:

: 22164-09-6,34049-09-7,74708-51-3,93301-73-6,108865-15-2
3,5-O-benzylidene-1,2-O-isopropylidene-α-D-glucofuranose

: 78931-03-0
3,5-O-benzylidene-6,7-dideoxy-9,11-O-ethylidene-1,2-O-isopropylidene-7-nitro-α-D-undeco-1,4-furanose

Guidance literature:: Multi-step reaction with 5 steps

1: CHCl₂COOH, DMSO, DCC, pyridine, / benzene / 5 h / Ambient temperature

2: CH₃ONa / methanol / 1 h

3: pyridine / CHCl₃ / 5 h

4: NaBH₄ / ethanol / 1 h

5: 32 percent / CH₃ONa / tetrahydrofuran; methanol / 3 h

With pyridine; dichloro-acetic acid; sodium tetrahydroborate; sodium methylate; dimethyl sulfoxide; dicyclohexyl-carbodiimide; In tetrahydrofuran; methanol; ethanol; chloroform; benzene;
DOI:10.1246/bcsj.54.1830

Reference yield:

: 54944-49-9
(3aR,3bS,7R,7aS,8aR)-2,2-Dimethyl-5-phenyl-tetrahydro-[1,3]dioxolo[4,5]furo[3,2-d][1,3]dioxine-7-carbaldehyde

: 78931-03-0
3,5-O-benzylidene-6,7-dideoxy-9,11-O-ethylidene-1,2-O-isopropylidene-7-nitro-α-D-undeco-1,4-furanose

Guidance literature:: Multi-step reaction with 4 steps

1: CH₃ONa / methanol / 1 h

2: pyridine / CHCl₃ / 5 h

3: NaBH₄ / ethanol / 1 h

4: 32 percent / CH₃ONa / tetrahydrofuran; methanol / 3 h

With pyridine; sodium tetrahydroborate; sodium methylate; In tetrahydrofuran; methanol; ethanol; chloroform;
DOI:10.1246/bcsj.54.1830