(5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)pentacarbonyldicobalt

Base Information

• Chemical Name: (5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)pentacarbonyldicobalt
• CAS No.: 941716-33-2
• Molecular Formula: C₂₈H₁₆Co₂O₆
• Molecular Weight: 566.418
• Mol file: 941716-33-2.mol

Synonyms:(5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)pentacarbonyldicobalt

Chemical Property of (5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)pentacarbonyldicobalt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)pentacarbonyldicobalt

There total 3 articles about (5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)pentacarbonyldicobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + 5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol (941716-31-0) → (5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)pentacarbonyldicobalt (941716-33-2) + (5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)hexacarbonyldicobalt (941716-32-1)

Guidance literature:

In tetrahydrofuran; N2; phenyl-compd. and Co-compd. in THF stirred at room temp. for 15 h, solv. removed at low temp.; chromy. (silica gel, pentane/CH2Cl2 90:10), recrystallized from pentane/CH2Cl2 80:20;

DOI:10.1002/anie.200605171

Reference yield: 73.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + 5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol (941716-31-0) → (5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)hexacarbonyldicobalt (941716-32-1) + (5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)pentacarbonyldicobalt (941716-33-2)

Guidance literature:

In tetrahydrofuran; (N2); soln. of alkyne and Co complex in THF was stirred at room temp. for 15 h; evapd. at low temp.; chromd. (silica gel, pentane/CH2Cl2); recrystd. (pentane/CH2Cl2);

DOI:10.1021/om900615m

Reference yield:

(5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)hexacarbonyldicobalt (941716-32-1) → (5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)pentacarbonyldicobalt (941716-33-2)

Guidance literature:

In not given; byproducts: CO;

DOI:10.1021/om900615m

upstream raw materials:

dicobalt octacarbonyl

5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol

(5-phenylethynyl-5H-dibenzo[a,d]cyclohepten-5-ol)hexacarbonyldicobalt