5-(4'-methylphenyl)-5,10-dihydroxodibenzo{b.e}bismine

Base Information

Chemical Name:5-(4'-methylphenyl)-5,10-dihydroxodibenzo{b.e}bismine
CAS No.:143674-25-3
Molecular Formula:C₂₀H₁₇Bi
Molecular Weight:466.335
Hs Code.:

Synonyms:5-(4'-methylphenyl)-5,10-dihydroxodibenzo{b.e}bismine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-(4'-methylphenyl)-5,10-dihydroxodibenzo{b.e}bismine

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Technology Process of 5-(4'-methylphenyl)-5,10-dihydroxodibenzo{b.e}bismine

There total 2 articles about 5-(4'-methylphenyl)-5,10-dihydroxodibenzo{b.e}bismine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 143674-24-2
5-iodo-5,10-dihydrodibenzo{b.e}bismine

: 4294-57-9
para-methylphenylmagnesium bromide

: 143674-25-3
5-(4'-methylphenyl)-5,10-dihydroxodibenzo{b.e}bismine

Guidance literature:: In tetrahydrofuran; dropwise addn. of CH3C6H4MgBr in THF to iodide in THF at 0°C under Ar, stirring for 10 min; extn.with ethyl acetate, drying, concg. under reduced pressure, recrystn. from MeOH, elem. anal.;

Reference yield:

: 32306-73-3
1,1'-methylenebis(2-chlorobenzene)

: 143674-25-3
5-(4'-methylphenyl)-5,10-dihydroxodibenzo{b.e}bismine

Guidance literature:: Multi-step reaction with 2 steps

1: K; MgCl₂ / tetrahydrofuran

2: tetrahydrofuran

With K; MgCl₂; In tetrahydrofuran;

Reference yield: 91.0%

: 143674-25-3
5-(4'-methylphenyl)-5,10-dihydroxodibenzo{b.e}bismine

: 143674-43-5
5,5-dichloro-5-(4'-methylphenyl)-5,10-dihydro-5λ5-dibenzo{b.e}bismine

Guidance literature:: With SO₂Cl₂; In hexane; dropwise addn. of sulfuryl dichloride in hexane to a suspn. of the starting bismine in hexane under Ar, stirring for 2 h; filtn., washing (hexane), recrystn., elem. anal.;