(1R,3S)-3-butyldiphenylsilyloxymethyl-2,2-dimethyl-cyclobutylmethylketone

Base Information

Chemical Name:(1R,3S)-3-butyldiphenylsilyloxymethyl-2,2-dimethyl-cyclobutylmethylketone
CAS No.:1352957-77-7
Molecular Formula:C₂₅H₃₄O₂Si
Molecular Weight:394.629
Hs Code.:

Synonyms:(1R,3S)-3-butyldiphenylsilyloxymethyl-2,2-dimethyl-cyclobutylmethylketone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,3S)-3-butyldiphenylsilyloxymethyl-2,2-dimethyl-cyclobutylmethylketone

Chemical Property:

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Technology Process of (1R,3S)-3-butyldiphenylsilyloxymethyl-2,2-dimethyl-cyclobutylmethylketone

There total 6 articles about (1R,3S)-3-butyldiphenylsilyloxymethyl-2,2-dimethyl-cyclobutylmethylketone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1352957-76-6
C₂₇H₃₈O₃Si

: 1352957-77-7
(1R,3S)-3-butyldiphenylsilyloxymethyl-2,2-dimethyl-cyclobutylmethylketone

Guidance literature:: With pyridinium p-toluenesulfonate; In acetone; for 5h; Reflux;
DOI:10.1016/j.tetasy.2011.10.016

Reference yield:

: 288848-29-3
methyl (1S,3R)-2,2-dimethyl-3-(2-methyl-1,3-dioxolan-2-yl)cyclobutanecarboxylate

: 1352957-77-7
(1R,3S)-3-butyldiphenylsilyloxymethyl-2,2-dimethyl-cyclobutylmethylketone

Guidance literature:: Multi-step reaction with 3 steps

1: lithium borohydride / tetrahydrofuran

2: dmap / dichloromethane / 12 h / 0 - 20 °C / Inert atmosphere

3: pyridinium p-toluenesulfonate / acetone / 5 h / Reflux

With dmap; lithium borohydride; pyridinium p-toluenesulfonate; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1016/j.tetasy.2011.10.016

Reference yield:

: 80-57-9,1196-01-6
(-)-Verbenone

: 1352957-77-7
(1R,3S)-3-butyldiphenylsilyloxymethyl-2,2-dimethyl-cyclobutylmethylketone

Guidance literature:: Multi-step reaction with 6 steps

1: sodium periodate / tetrachloromethane; water; acetonitrile

2: diethyl ether

3: pyridinium p-toluenesulfonate / Heating

4: lithium borohydride / tetrahydrofuran

5: dmap / dichloromethane / 12 h / 0 - 20 °C / Inert atmosphere

6: pyridinium p-toluenesulfonate / acetone / 5 h / Reflux

With dmap; sodium periodate; lithium borohydride; pyridinium p-toluenesulfonate; In tetrahydrofuran; tetrachloromethane; diethyl ether; dichloromethane; water; acetone; acetonitrile;
DOI:10.1016/j.tetasy.2011.10.016