[η5-(trimethoxysilylpropyl)cyclopentadienyl](η5-cyclopentadienyl)dichlorotitanium(IV)

Base Information

• Chemical Name: [η5-(trimethoxysilylpropyl)cyclopentadienyl](η5-cyclopentadienyl)dichlorotitanium(IV)
• CAS No.: 77098-61-4
• Molecular Formula: C₁₆H₂₄Cl₂O₃SiTi
• Molecular Weight: 411.236
• Mol file: 77098-61-4.mol

Synonyms:[η5-(trimethoxysilylpropyl)cyclopentadienyl](η5-cyclopentadienyl)dichlorotitanium(IV)

Chemical Property of [η5-(trimethoxysilylpropyl)cyclopentadienyl](η5-cyclopentadienyl)dichlorotitanium(IV)

Chemical Property:

Purity/Quality:

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Technology Process of [η5-(trimethoxysilylpropyl)cyclopentadienyl](η5-cyclopentadienyl)dichlorotitanium(IV)

There total 2 articles about [η5-(trimethoxysilylpropyl)cyclopentadienyl](η5-cyclopentadienyl)dichlorotitanium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclopentadienyl titanium(IV) trichloride (1270-98-0) + sodium [η5-(trimethoxysilylpropyl)cyclopentadienide] → bis(cyclopentadienyl)titanium dichloride (1271-19-8) + [η5-(trimethoxysilylpropyl)cyclopentadienyl](η5-cyclopentadienyl)dichlorotitanium(IV) (77098-61-4)

Guidance literature:

In tetrahydrofuran; (N2), an excess of a soln. of the organic compound added dropwise to a soln. of the complex at -30°C, stirred at room temp. for 16h; solvent removed, residue extd. with CH2Cl2, solvent removed;

DOI:10.1016/0022-328X(86)80433-8

Reference yield:

[η5-(trimethoxysilylpropyl)cyclopentadienyl]trichlorotitanium(IV) (110276-18-1) + sodium cyclopentadienide → bis(cyclopentadienyl)titanium dichloride (1271-19-8) + [η5-(trimethoxysilylpropyl)cyclopentadienyl](η5-cyclopentadienyl)dichlorotitanium(IV) (77098-61-4)

Guidance literature:

In tetrahydrofuran; (N2), an execess of a soln. of NaC5H5 added dropwise to a soln. of the complex at -10°C, stirred at room temp. for 12 h; solvent removed, residue extd. with hexane/CH2Cl2, filtered, solvents removed;

DOI:10.1016/0022-328X(86)80433-8

upstream raw materials:

cyclopentadienyl titanium(IV) trichloride

[η5-(trimethoxysilylpropyl)cyclopentadienyl]trichlorotitanium(IV)