2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose

Base Information

Chemical Name:2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose
CAS No.:1381864-49-8
Molecular Formula:C₁₅H₁₆ClN₃O₆
Molecular Weight:369.762
Hs Code.:

Synonyms:2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose

Suppliers and Price of 2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose

There total 6 articles about 2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1381864-48-7
tert-butyldimethylsilyl 2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-β-D-galactopyranoside

: 2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-β-D-galactopyranose

: 1381864-49-8
2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose

Guidance literature:: With tetrabutyl ammonium fluoride; acetic acid; In tetrahydrofuran; at 0 ℃; for 2h; optical yield given as %de; Inert atmosphere;
DOI:10.1016/j.tet.2012.04.059

Reference yield:

: 849033-16-5
phenyl 1-thio-2-azido-4,6-O-benzylidene-3-O-chloroacetyl-2-deoxy-β-D-galactopyranoside

: 2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-β-D-galactopyranose

: 1381864-49-8
2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose

Guidance literature:: With N-Bromosuccinimide; In water; acetone; at 20 ℃; for 0.25h; Overall yield = 77 %; Overall yield = 560 mg;
DOI:10.1002/chem.201203865

Reference yield:

: 147254-13-5
(tert-butyldimethyl)silyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-galactopyranoside

: 2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-β-D-galactopyranose

: 1381864-49-8
2-azido-4,6-O-benzylidene-3-O-(2-chloroacetyl)-2-deoxy-α-D-galactopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / dichloromethane / 0.25 h / -20 °C / Inert atmosphere

2: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

With pyridine; tetrabutyl ammonium fluoride; acetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tet.2012.04.059