tetraphenylphosphonium trithiocarbonatocuprate(I)

Base Information

• Chemical Name: tetraphenylphosphonium trithiocarbonatocuprate(I)
• CAS No.: 51435-86-0
• Molecular Formula: CCuS₃*C₂₄H₂₀P
• Molecular Weight: 511.152
• Mol file: 51435-86-0.mol

Synonyms:tetraphenylphosphonium trithiocarbonatocuprate(I)

Chemical Property of tetraphenylphosphonium trithiocarbonatocuprate(I)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tetraphenylphosphonium trithiocarbonatocuprate(I)

There total 2 articles about tetraphenylphosphonium trithiocarbonatocuprate(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

potassium trithiocarbonate (584-10-1) + cuprous ethyl xanthate + tetraphenyl phosphonium chloride (2001-45-8) → tetraphenylphosphonium trithiocarbonatocuprate(I) (51435-86-0)

Guidance literature:

In water; N,N-dimethyl-formamide; acetone; addn. of K2CS3 in H2O/DMF to suspension of Cu(S2COC2H5) in acetone at room temp.; addn. of ((C6H5)4P)Cl in H2O; filtration; washed with H2O and methanol; dried in vacuo; elem. anal.;

Reference yield: 77.1%

potassium trithiocarbonate (584-10-1) + tetraphenyl phosphonium chloride (2001-45-8) + copper dichloride → (C6H5)4P(1+)*Cu(1+)*CS3(2-)=((C6H5)4P)[Cu(CS3)] (51435-86-0)

Guidance literature:

In water; dimethyl sulfoxide; inert atm.; excess of K2CS3, stirring (15 min); cooling (18°C), filtn., washing (H2O, 2-propanol, Et2), drying (vac., P2O5); elem. anal.;

Reference yield:

tetraphenylphosphonium trithiocarbonatocuprate(I) (51435-86-0) → copper(I) sulfide (22205-45-4)

Guidance literature:

With hydrogenchloride; In not given; byproducts: CS2; slowly addn. of HCl to soln. of (Cu(CS3))(1-);;

upstream raw materials:

potassium trithiocarbonate

tetraphenyl phosphonium chloride

Downstream raw materials:

copper(I) sulfide

Refernces