3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate

Base Information

• Chemical Name: 3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate
• CAS No.: 938434-75-4
• Molecular Formula: C₂₂H₂₃Cl₃N₄O₁₀
• Molecular Weight: 609.804

Synonyms:3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate

Chemical Property of 3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate

There total 3 articles about 3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

C20H23N3O10 + trichloroacetonitrile (545-06-2) → 3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate (938434-75-4)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1002/anie.200604761

Reference yield:

allyl 2-O-(2-azidomethyl)benzoyl-4,6-O-benzylidene-α-D-glucopyranoside (676530-89-5) → 3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate (938434-75-4)

Guidance literature:

Multi-step reaction with 4 steps

1: 88 percent / aq. AcOH / 5 h / 70 °C

2: 98 percent / Et₃N; DMAP / 2 h / 20 °C

3: 80 percent / MeOH / PdCl₂ / CH₂Cl₂ / 20 °C

4: 90 percent / DBU / CH₂Cl₂ / 2 h / 20 °C

With methanol; dmap; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; palladium dichloride; In dichloromethane;

DOI:10.1002/anie.200604761

Reference yield:

C23H27N3O10 (938434-90-3) → 3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate (938434-75-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / MeOH / PdCl₂ / CH₂Cl₂ / 20 °C

2: 90 percent / DBU / CH₂Cl₂ / 2 h / 20 °C

With methanol; 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium dichloride; In dichloromethane;

DOI:10.1002/anie.200604761

upstream raw materials:

trichloroacetonitrile

C₂₃H₂₇N₃O₁₀

allyl 2-O-(2-azidomethyl)benzoyl-4,6-O-benzylidene-α-D-glucopyranoside

Downstream raw materials:

C₂₇H₄₀O₃C₆H₁₀O₅(C₂H₂O)3COC₆H₃CH₂N₃

C₂₇H₄₀O₃C₆H₁₀O₅(C₂H₂O)3C₆H₁₀O₄(C₇H₄O)3

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 938434-75-4 3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate

Send

Send

Metric Ton KG G Pound L ML

Send

Send