Methyl methacrylate

Base Information

• Chemical Name: Methyl methacrylate
• CAS No.: 35777-12-9
• Deprecated CAS: 162221-54-7,220713-32-6,874217-13-7,1196968-39-4,1227277-87-3,1451188-71-8,1453489-95-6,211862-43-0,1196968-39-4,1227277-87-3,220713-32-6,874217-13-7
• Molecular Formula: C₅H₈O₂
• Molecular Weight: 103.093
• European Community (EC) Number: 201-297-1,618-466-4,924-135-8,686-139-3
• ICSC Number: 0300
• NSC Number: 4769
• UN Number: 1247
• UNII: 196OC77688
• DSSTox Substance ID: DTXSID2020844
• Nikkaji Number: J3.532G
• Wikipedia: Poly(methyl_methacrylate),Methyl_methacrylate
• Wikidata: Q382897
• NCI Thesaurus Code: C47615
• RXCUI: 29897
• Metabolomics Workbench ID: 45475
• ChEMBL ID: CHEMBL49996
• Mol file: 35777-12-9.mol

Synonyms:METHYL METHACRYLATE;80-62-6;methyl 2-methylprop-2-enoate;Methylmethacrylate;Methyl methylacrylate;Methyl 2-methylpropenoate;Methacrylic acid methyl ester;Pegalan;Methyl-methacrylat;Methyl 2-methyl-2-propenoate;Diakon;Acryester M;2-Propenoic acid, 2-methyl-, methyl ester;Methacrylate de methyle;Methyl 2-methylacrylate;Cranioplast;Metaplex;2-Methyl-2-propenoic acid methyl ester;Methacrylsaeuremethyl ester;2-(Methoxycarbonyl)-1-propene;Kallocryl A;Metakrylan metylu;Methylmethacrylaat;Metil metacrilato;Simplex P;Rcra waste number U162;Methyl alpha-methylacrylate;Methyl methacrylate monomer;TEB 3K;NCI-C50680;2-Methylacrylic acid, methyl ester;Methacrylic acid, methyl ester;9011-14-7;Acrylic acid, 2-methyl-, methyl ester;Methylmethacrylaat [Dutch];2-Methyl-acrylic acid methyl ester;Metakrylan metylu [Polish];NSC 4769;Methyl-methacrylat [German];Metil metacrilato [Italian];Monocite methacrylate monomer;CCRIS 1364;HSDB 195;Methylester kyseliny methakrylove;CHEBI:34840;Methacrylate de methyle [French];2-methylacrylic acid methyl ester;Methyl meth-d3-acrylate;Methacrylsaeuremethyl ester [German];EINECS 201-297-1;UN1247;RCRA waste no. U162;BRN 0605459;Methylester kyseliny methakrylove [Czech];Methyl .alpha.-methylacrylate;monocite" Methacrylate monomer;AI3-24946;DTXSID2020844;UNII-196OC77688;NSC-4769;Methyl methacrylate monomer, inhibited;143476-91-9;Methyl ester of 2-methyl-2-propenoic acid;196OC77688;EC 201-297-1;114512-63-9;4-02-00-01519 (Beilstein Handbook Reference);51391-19-6;Plexiglass;Kallocryl;Sintex;Zimmer Bone Cement;55063-97-3;Methacrylate Methyl Monomer;Metylmetakrylat;Eudragit;Methylmethacrylate Methyl Monomer;methoxymethacrolein;MMA (stabilized);J69;Methacrylate monomer;Methacrylate, methyl-;MMM (CHRIS Code);2-Propenoic acid, 2-methyl- methyl ester;Acrylic resins (PMMA);METHYL METHACTRYLATE;Epitope ID:131321;Methyl 2-methylacrylate #;Methyl methacrylate (MMA);Methyl-.alpha.-methacrylate;SCHEMBL1849;CH2=C(CH3)COOCH3;Methacrylic acid-methyl ester;methyl-2-methyl-2-propenoate;NA 1247 (Salt/Mix);UN 1247 (Salt/Mix);BIDD:ER0634;CHEMBL49996;DTXCID80844;Methyl methacrylate, 99.5%;WLN: 1UY1&VO1;Methyl methacrylate, stabilized;Methyl ester of methacrylic acid;Methyl methacrylate, CP,98.0%;NSC4769;METHYL METHACRYLATE [HSDB];METHYL METHACRYLATE [IARC];METHYL METHACRYLATE [INCI];METHYLMETHACRYLATE [MART.];METHYL METHACRYLATE [VANDF];METHYLMETHACRYLATE [WHO-DD];Tox21_200367;MFCD00008587;NA1247;STL283952;AKOS000120216;Methyl methacrylate, 99%, stabilized;LS-1799;CAS-80-62-6;NCGC00091089-01;NCGC00091089-02;NCGC00257921-01;9065-11-6;Methacrylic Acid Methyl Ester (stabilized;METHACRYLIC ACID METHYL ESTER [MI];M0087;METHYL 2-METHYL-2-PROPENOATE [FHFI];EN300-19210;C19504;Methyl methacrylate 1000 microg/mL in Methanol;Methyl methacrylate, SAJ first grade, >=99.0%;A839957;Q382897;J-522614;F0001-2087;Methacrylic acid-methyl ester 100 microg/mL in Cyclohexane;Methyl Methacrylate (stabilized with 6-tert-Butyl-2,4-xylenol);Methyl methacrylate monomer, inhibited [UN1247] [Flammable liquid];Methyl Methacrylate, (stabilized with 6-tert-Butyl-2,4-xylenol);Methyl methacrylate, contains <=30 ppm MEHQ as inhibitor, 99%;Methyl methacrylate, European Pharmacopoeia (EP) Reference Standard;Methyl methacrylate (MMA), 99.5%(GC), contains 30ppm MEHQ as stabilizer;Methyl methacrylate (MMA), AR, 99.0%, contains 30ppm MEHQ as stabilizer;Methyl methacrylate monomer, inhibited [UN1247] [Flammable liquid];PROPENOIC ACID,2-METHYL,METHYLESTER (METHACRYLATE METHYLESTER);80209-57-0;97555-82-3

Chemical Property of Methyl methacrylate

Chemical Property:

• PSA: 26.30000
• LogP: 0.73550
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 100.052429494
• Heavy Atom Count: 7
• Complexity: 94.3
• Transport DOT Label: Flammable Liquid

Purity/Quality:

99% ^*data from raw suppliers

Methyl-d3Methacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: CC(=C)C(=O)OC
• Inhalation Risk: A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20 °C.
• Effects of Short Term Exposure: The substance is irritating to the eyes, skin and respiratory tract.
• Effects of Long Term Exposure: Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the peripheral nervous system.
• Uses: Methyl-d3 Methacrylate (CAS# 35777-12-9) is a useful isotopically labeled research compound.

Technology Process of Methyl methacrylate

There total 2 articles about Methyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.1%

d(4)-methanol (811-98-3) + Methacryloyl chloride (920-46-7,26937-45-1) → 2-methyl-acrylic acid trideuteriomethyl ester (35777-12-9)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 10h; Inert atmosphere; Cooling with ice;

Reference yield:

d(4)-methanol (811-98-3) + C27H24O2 (1233011-21-6) → 2-methyl-acrylic acid trideuteriomethyl ester (35777-12-9)

Guidance literature:

In chloroform-d1; at 35 ℃; Kinetics;

DOI:10.1021/ma101057j

upstream raw materials:

d⁽⁴⁾-methanol

C₂₇H₂₄O₂

Methacryloyl chloride

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