1-Butyl-3-methylimidazolium hydrogensulfate

Base Information

• Chemical Name: 1-Butyl-3-methylimidazolium hydrogensulfate
• CAS No.: 262297-13-2
• Molecular Formula: C8H16N2O4S
• Molecular Weight: 236.292
• Mol file: 262297-13-2.mol

Synonyms:BASIONIC(TM) AC 28;BMIM HSO4;1-BUTYL-3-METHYLIMIDAZOLIUM HYDROGENSULFATE;BASIONIC(R) AC 28;Basionics(R) AC 28;1-Butyl-3-methyl-1H-imidazolium hydrogen sulfate;1-Butyl-3-methylimidazolium bisulfate;1-n-Butyl-3-methylimidazolium hydrogen sulfate

Chemical Property of 1-Butyl-3-methylimidazolium hydrogensulfate

Chemical Property:

• Melting Point: 29-32 °C
• Flash Point: 284 °C
• PSA: 94.62000
• Density: 1.27g/ml
• LogP: 1.19810
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: soluble in Methanol

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Butyl-3-methylimidazolium Hydrogen Sulfate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Basionic Ionic Liquids [BMIM][HSO4] can be used as an additive to accelerate current efficiency, lower power consumption, and enhance the surface morphology during the electrodeposition of zinc from acidic sulfate solutions. The combination of sodium nitrate and [BMIM][HSO4] can be used as a nitrating agent for the selective nitration of phenols to afford its corresponding nitro derivatives. [BMIM][HSO4] can also be used as catalyst for the preparation of 1,8-dioxo-octahydroxanthenes.

Technology Process of 1-Butyl-3-methylimidazolium hydrogensulfate

There total 12 articles about 1-Butyl-3-methylimidazolium hydrogensulfate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-methyl-3-(n-butyl)imidazolium iodide (65039-05-6) → 1-butyl-3-methylimidazolium hydrogen sulfate (262297-13-2)

Guidance literature:

With Amberlyst A-26 (HSO₄^- form); In methanol;

DOI:10.3390/molecules17044007

Reference yield: 100.0%

→ 1-butyl-3-methylimidazolium hydrogen sulfate (262297-13-2)

Guidance literature:

Reference yield: 99.4%

1-butyl-3-methylimidazolium chloride (79917-90-1) → 1-butyl-3-methylimidazolium hydrogen sulfate (262297-13-2)

Guidance literature:

With sulfuric acid; In dichloromethane; for 48h; Reflux; Cooling with ice;

upstream raw materials:

1-methyl-3-(n-butyl)imidazolium iodide

1-butyl-3-methylimidazolium chloride

1-n-butyl-3-methylimidazolim bromide

1-Butylimidazole

Refernces

• 1、 Villar-Garcia, Ignacio J.,Fearn, Sarah,Ismail, Nur L.,McIntosh, Alastair J. S.,Lovelock, Kevin R. J.. "Fine tuning the ionic liquid-vacuum outer atomic surface using ion mixtures". . p. 5367 - 5370. Retrieved 2015.
• 2、 Jacquemin, Johan,Goodrich, Peter,Jiang, Wei,Rooney, David W.,Hardacre, Christopher. "Are alkyl sulfate-based protic and aprotic ionic liquids stable with water and alcohols? A thermodynamic approach". . p. 1938 - 1949. Retrieved 2013.
• 3、 Abro, Rashid,Gao, Shurong,Chen, Xiaochun,Yu, Guangren,Abdeltawab Salem, Ahmed A.,Al-Deyabb. "Oxidative desulfurization of gasoline by ionic liquids coupled with extraction by organic solvents". . p. 998 - 1006. Retrieved 2016.
• 4、 Liu,Yu,Zhou,Zhang,Zhang. "Influence of anions of imidazole ionic liquids on dissolution of cellulose". . p. 8266 - 8270. Retrieved 2013.
• 5、 Wang, Qing,Wu, Zhi Min,Li, Yongfei,Tan, Ying,Liu, Ning,Liu, Yuejin. "The efficient hydroxyalkylation of phenol with formaldehyde to bisphenol F over a thermoregulated phase-separable reaction system containing a water-soluble Bronsted acidic ionic liquid". . p. 33466 - 33473. Retrieved 2014.
• 6、 Ferreira, Vinícius Castro,Zanchet, Letícia,Monteiro, Wesley Formentin,da Trindade, Letícia Guerreiro,de Souza, Michèle Oberson,Correia, Ricardo Rego Bordalo. "Theoretical and experimental comparative study of nonlinear properties of imidazolium cation based ionic liquids". . . Retrieved 2021/02/09.
• 7、 Martini, María B.,Fernández, José L.,Adam, Claudia G.. "Insights on the catalytic behaviour of sulfonic acid-functionalized ionic liquids (ILs) in transesterification reactions - voltammetric characterization of sulfonic task-specific ILs with bisulfate anions". . p. 2731 - 2741. Retrieved 2021/02/12.