1-Naphthalenamine,1,2,3,4-tetrahydro-N,4-dimethyl-,(1R,4S)-(9CI)

Base Information

Chemical Name:1-Naphthalenamine,1,2,3,4-tetrahydro-N,4-dimethyl-,(1R,4S)-(9CI)
CAS No.:261776-48-1
Molecular Formula:C₁₂H₁₇N
Molecular Weight:175.274
Hs Code.:
Mol file:261776-48-1.mol

Synonyms:1-Naphthalenamine,1,2,3,4-tetrahydro-N,4-dimethyl-,(1R,4S)-(9CI)

Suppliers and Price of 1-Naphthalenamine,1,2,3,4-tetrahydro-N,4-dimethyl-,(1R,4S)-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-Naphthalenamine,1,2,3,4-tetrahydro-N,4-dimethyl-,(1R,4S)-(9CI)

Chemical Property:

PSA：12.03000
LogP:3.23530

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-Naphthalenamine,1,2,3,4-tetrahydro-N,4-dimethyl-,(1R,4S)-(9CI)

There total 4 articles about 1-Naphthalenamine,1,2,3,4-tetrahydro-N,4-dimethyl-,(1R,4S)-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: methyl(4-methyl-3,4-dihydro-2H-naphthalen-1-ylidene)amine

: 98213-39-9
(R)-4-methyl-1-tetralone

: 261776-48-1
N-methyl-4-methyl-1,2,3,4-tetrahydro-1-naphthylamine

: 261776-48-1
N-methyl-4-methyl-1,2,3,4-tetrahydro-1-naphthylamine

Guidance literature:: With (R,R)-(ethylenebis(tetrahydroindenyl))TiF₂; phenylsilane; In tetrahydrofuran; at 13 ℃; for 24h;
DOI:10.1021/jo991328h

Reference yield: 90.0%

: methyl(4-methyl-3,4-dihydro-2H-naphthalen-1-ylidene)amine

: 98213-39-9
(R)-4-methyl-1-tetralone

: 261776-48-1
N-methyl-4-methyl-1,2,3,4-tetrahydro-1-naphthylamine

: 261776-48-1
N-methyl-4-methyl-1,2,3,4-tetrahydro-1-naphthylamine

Guidance literature:: With (R,R)-(ethylenebis(tetrahydroindenyl))TiF₂; phenylsilane; In tetrahydrofuran; at 13 ℃; for 24h;
DOI:10.1021/jo991328h

Reference yield:

: 19832-98-5
4-methyl-3,4-dihydro-2H-naphthalen-1-one

: 261776-48-1
N-methyl-4-methyl-1,2,3,4-tetrahydro-1-naphthylamine

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / TiCl₄ / diethyl ether / -35 - 20 °C

2: (R,R)-(ethylenebis(tetrahydroindenyl))TiF₂; PhSiH₃ / tetrahydrofuran / 24 h / 13 °C

With (R,R)-(ethylenebis(tetrahydroindenyl))TiF₂; phenylsilane; titanium tetrachloride; In tetrahydrofuran; diethyl ether; 1: Condensation / 2: kinetic resolution;
DOI:10.1021/jo991328h