C₅₉H₈₅IO₁₂

Base Information

Chemical Name:C₅₉H₈₅IO₁₂
CAS No.:676549-23-8
Molecular Formula:C₅₉H₈₅IO₁₂
Molecular Weight:1113.22
Hs Code.:

C<sub>59</sub>H<sub>85</sub>IO<sub>12</sub>

Synonyms:C₅₉H₈₅IO₁₂

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Chemical Property of C₅₉H₈₅IO₁₂

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Technology Process of C₅₉H₈₅IO₁₂

There total 26 articles about C₅₉H₈₅IO₁₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 676549-21-6
C₅₉H₈₄O₁₂

: 676549-23-8
C₅₉H₈₅IO₁₂

Guidance literature:: C₅₉H₈₄O₁₂; With Schwartz's reagent; In tetrahydrofuran; at 20 ℃; for 1.5h;

With iodine; In tetrahydrofuran; for 0.25h;
DOI:10.1021/ja039618+

Reference yield:

: 197899-19-7
(2R)-1-chloro-2-hydroxy-4-pentene

: 676549-23-8
C₅₉H₈₅IO₁₂

Guidance literature:: Multi-step reaction with 14 steps

1.1: 81 percent / KOH

2.1: n-BuLi / tetrahydrofuran / -78 - 20 °C

2.2: BF₃*Et₂O / tetrahydrofuran / 0.33 h / -78 °C

2.3: 75 percent / tetrahydrofuran / 1 h / -78 °C

3.1: 77 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 20 °C

4.1: NaH / dimethylformamide / 0.17 h

4.2: 73 percent / Bu₄NI / dimethylformamide / 25 h / 20 °C

5.1: n-BuLi / tetrahydrofuran / 0.17 h / -50 °C

5.2: 434 mg / tetrahydrofuran / 0.5 h / -40 °C

6.1: 32 percent / (S,S)-salen Co(III)OAc; H₂O / tetrahydrofuran / 1 h

7.1: n-BuLi / tetrahydrofuran; hexane / 2.5 h / -78 - -40 °C

7.2: Bf₃*Et₂O / tetrahydrofuran; hexane / 0.17 h / -78 °C

7.3: 59 percent / tetrahydrofuran; hexane / 3 h / -78 °C

8.1: 100 °C

9.1: Pt(DVDS) / tetrahydrofuran; xylene / 20 °C

10.1: aq. H₂O₂; KF; KHCO₃ / tetrahydrofuran; methanol / 20 °C

11.1: Et₂BOMe / tetrahydrofuran; methanol / -78 °C

11.2: NaBH₄ / tetrahydrofuran; methanol / -78 °C

12.1: K₂CO₃; MeOH

13.1: TsOH*H₂O; 3 Angstroem molecular sieves / 20 °C

14.1: Cp₂Zr(H)Cl / tetrahydrofuran / 1.5 h / 20 °C

14.2: 90 percent / I₂ / tetrahydrofuran / 0.25 h

With methanol; potassium fluoride; potassium hydroxide; Schwartz's reagent; n-butyllithium; bis(η2:η2-1,3-divinyltetramethyl)platinum(0); (S,S)-salen Co(III)OAc; 3 A molecular sieve; diethyl methoxy borane; water; dihydrogen peroxide; sodium hydride; potassium carbonate; potassium hydrogencarbonate; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; hexane; dichloromethane; N,N-dimethyl-formamide; xylene;
DOI:10.1021/ja039618+

Reference yield:

: 144422-60-6
(R)-2-but-3-enyloxirane

: 676549-23-8
C₅₉H₈₅IO₁₂

Guidance literature:: Multi-step reaction with 13 steps

1.1: n-BuLi / tetrahydrofuran / -78 - 20 °C

1.2: BF₃*Et₂O / tetrahydrofuran / 0.33 h / -78 °C

1.3: 75 percent / tetrahydrofuran / 1 h / -78 °C

2.1: 77 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 20 °C

3.1: NaH / dimethylformamide / 0.17 h

3.2: 73 percent / Bu₄NI / dimethylformamide / 25 h / 20 °C

4.1: n-BuLi / tetrahydrofuran / 0.17 h / -50 °C

4.2: 434 mg / tetrahydrofuran / 0.5 h / -40 °C

5.1: 32 percent / (S,S)-salen Co(III)OAc; H₂O / tetrahydrofuran / 1 h

6.1: n-BuLi / tetrahydrofuran; hexane / 2.5 h / -78 - -40 °C

6.2: Bf₃*Et₂O / tetrahydrofuran; hexane / 0.17 h / -78 °C

6.3: 59 percent / tetrahydrofuran; hexane / 3 h / -78 °C

7.1: 100 °C

8.1: Pt(DVDS) / tetrahydrofuran; xylene / 20 °C

9.1: aq. H₂O₂; KF; KHCO₃ / tetrahydrofuran; methanol / 20 °C

10.1: Et₂BOMe / tetrahydrofuran; methanol / -78 °C

10.2: NaBH₄ / tetrahydrofuran; methanol / -78 °C

11.1: K₂CO₃; MeOH

12.1: TsOH*H₂O; 3 Angstroem molecular sieves / 20 °C

13.1: Cp₂Zr(H)Cl / tetrahydrofuran / 1.5 h / 20 °C

13.2: 90 percent / I₂ / tetrahydrofuran / 0.25 h

With methanol; potassium fluoride; Schwartz's reagent; n-butyllithium; bis(η2:η2-1,3-divinyltetramethyl)platinum(0); (S,S)-salen Co(III)OAc; 3 A molecular sieve; diethyl methoxy borane; water; dihydrogen peroxide; sodium hydride; potassium carbonate; potassium hydrogencarbonate; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; hexane; dichloromethane; N,N-dimethyl-formamide; xylene;
DOI:10.1021/ja039618+