{(η5-C5H5)Re(NO)(PPh3)(H2C=C(CH3)2)}+PF6-

Base Information

• Chemical Name: {(η5-C5H5)Re(NO)(PPh3)(H2C=C(CH3)2)}+PF6-
• CAS No.: 85926-83-6
• Molecular Formula: C₂₇H₂₈NOPRe*F₆P
• Molecular Weight: 744.67
• Mol file: 85926-83-6.mol

Synonyms:{(η5-C5H5)Re(NO)(PPh3)(H2C=C(CH3)2)}+PF6-

Chemical Property of {(η5-C5H5)Re(NO)(PPh3)(H2C=C(CH3)2)}+PF6-

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of {(η5-C5H5)Re(NO)(PPh3)(H2C=C(CH3)2)}+PF6-

There total 1 articles about {(η5-C5H5)Re(NO)(PPh3)(H2C=C(CH3)2)}+PF6- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(C5H5)((CH3)2CH)CH2((C6H5)3P)(NO)Re (85926-74-5) + tritylium hexafluorophosphate (437-17-2) → {(η5-C5H5)Re(NO)(PPh3)(H2C=C(CH3)2)}+PF6- (85926-83-6)

Guidance literature:

In dichloromethane; to a -78°C soln. of Re-complex in CH2Cl2 was added Ph3CPF6, stirred at -78°C for 15 min, warmed to room temp.; hexanes was added, evapd., washed with hexanes and ether, was taken up in CHCl3/CH2Cl2, crystd. by addition of ether, filtered;

DOI:10.1021/ja00353a020

Reference yield: 73.0%

{(η5-C5H5)Re(NO)(PPh3)(H2C=C(CH3)2)}+PF6- (85926-83-6) + potassium tert-butylate (865-47-4) → (η5-C5H5)Re(NO)(PPh3)(CH2C(CH3)=CH2) (122295-31-2)

Guidance literature:

In tetrahydrofuran; under N2, addn. of t-C4H9OK in t-BuOH to allyl complex in THF, stirring, 3 h; removing solvent in vac., extg. residue with ether, filtering, pptn. by addn. of hexanes, filtration, drying in vac.;

upstream raw materials:

(C₅H₅)((CH₃)2CH)CH₂((C₆H₅)3P)(NO)Re

tritylium hexafluorophosphate

Downstream raw materials:

(η5-C5H5)Re(NO)(PPh3)(CH2C(CH3)=CH2)