1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose

Base Information

Chemical Name:1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose
CAS No.:1400906-86-6
Molecular Formula:C₃₆H₃₆N₂O₅S
Molecular Weight:608.758
Hs Code.:

Synonyms:1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose

Suppliers and Price of 1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose

There total 6 articles about 1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: C₃₅H₃₅ClO₅S

: 1400906-86-6
1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose

: 1400906-96-8
p-tolyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucoheptopyranoside 7-methanate

Guidance literature:: In diethyl ether; toluene; at -45 ℃; for 0.5h;
DOI:10.1021/jo300986c

Reference yield:

: 1400906-91-3
p-tolyl 2,3,4-tri-O-benzyl-6,7-dideoxy-1-thio-β-D-glucohept-6-enopyranoside

: 1400906-86-6
1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose

: 1400906-96-8
p-tolyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucoheptopyranoside 7-methanate

Guidance literature:: Multi-step reaction with 4 steps

1: 9-bora-bicyclo[3.3.1]nonane; dihydrogen peroxide; sodium hydroxide / water; tetrahydrofuran / 0 - 20 °C

2: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 1 h / 20 °C

3: oxalyl dichloride; 2,6-dimethylpyridine / toluene / 15 h / -15 - 20 °C

4: toluene; diethyl ether / 0.5 h / -45 °C

With 2,6-dimethylpyridine; oxalyl dichloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; dihydrogen peroxide; 9-bora-bicyclo[3.3.1]nonane; sodium hydroxide; In tetrahydrofuran; diethyl ether; dichloromethane; water; toluene;
DOI:10.1021/jo300986c

Reference yield:

: 1400906-92-4
p-tolyl 2,3,4-tri-O-benzyl-6-deoxy-1-thio-β-D-glucoheptopyranoside

: 1400906-86-6
1-p-tolyl-2,3,4-tri-O-benzyl-8-deoxy-8-diazo-1-thio-β-D-glucooctopyrano-7-ulose

: 1400906-96-8
p-tolyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucoheptopyranoside 7-methanate

Guidance literature:: Multi-step reaction with 3 steps

1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 1 h / 20 °C

2: oxalyl dichloride; 2,6-dimethylpyridine / toluene / 15 h / -15 - 20 °C

3: toluene; diethyl ether / 0.5 h / -45 °C

With 2,6-dimethylpyridine; oxalyl dichloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; In diethyl ether; dichloromethane; water; toluene;
DOI:10.1021/jo300986c