(ALPHA,GAMMA-BISDIPHENYLENE-BETA-PHENYLALLYL), FREE RADICAL

Base Information

• Chemical Name: (ALPHA,GAMMA-BISDIPHENYLENE-BETA-PHENYLALLYL), FREE RADICAL
• CAS No.: 35585-94-5
• Molecular Formula: C39H27*
• Molecular Weight: 495.643
• Mol file: 35585-94-5.mol

Synonyms:BDPA COMPLEX WITH BENZENE(1:1);(ALPHA,GAMMA-BISDIPHENYLENE-BETA-PHENYLALLYL), FREE RADICAL;bdpa;BDPA complex with benzene(1:1),free radical;BDPA, FREE RADICAL (ALPHA,GAMMA-BIS-DIPH ENYLENE-BETA-PHENYLALLYL);α,γ-bisdiphenylene-β-phenylallyl;BDPA, free radical, complex with benzene (1:1)

Chemical Property of (ALPHA,GAMMA-BISDIPHENYLENE-BETA-PHENYLALLYL), FREE RADICAL

Chemical Property:

• Melting Point: 210 °C (dec.)(lit.)
• PSA: 0.00000
• LogP: 9.78620

Purity/Quality:

98%,99%, ^*data from raw suppliers

BDPA complex with benzene(1:1), free radical ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of (ALPHA,GAMMA-BISDIPHENYLENE-BETA-PHENYLALLYL), FREE RADICAL

There total 3 articles about (ALPHA,GAMMA-BISDIPHENYLENE-BETA-PHENYLALLYL), FREE RADICAL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

9-chloro-9-<α(9-fluorenylidene)-benzyl>fluorene (72087-83-3) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → α,γ-bisdiphenylene-β-phenylallyl*benzene (35585-94-5)

Guidance literature:

9-chloro-9-<α(9-fluorenylidene)-benzyl>fluorene; With silver; In tetrahydrofuran; at 20 ℃; for 5h; Inert atmosphere;

benzene;

DOI:10.1007/s11164-018-3282-7

Reference yield:

9-fluorenone (486-25-9,952573-42-1) → α,γ-bisdiphenylene-β-phenylallyl*benzene (35585-94-5)

Guidance literature:

Multi-step reaction with 3 steps

1.1: magnesium; iodine / tetrahydrofuran / 1.5 h / 45 °C / Inert atmosphere

1.2: 14 h / Inert atmosphere; Reflux

2.1: calcium chloride; hydrogenchloride / benzene / 2 h / 5 - 15 °C

3.1: silver / tetrahydrofuran / 5 h / 20 °C / Inert atmosphere

With hydrogenchloride; iodine; silver; magnesium; calcium chloride; In tetrahydrofuran; benzene;

DOI:10.1007/s11164-018-3282-7

Reference yield:

9-[bromo-(phenyl)methylene]-9H-fluorene (33735-95-4) → α,γ-bisdiphenylene-β-phenylallyl*benzene (35585-94-5)

Guidance literature:

Multi-step reaction with 3 steps

1.1: magnesium; iodine / tetrahydrofuran / 1.5 h / 45 °C / Inert atmosphere

1.2: 14 h / Inert atmosphere; Reflux

2.1: calcium chloride; hydrogenchloride / benzene / 2 h / 5 - 15 °C

3.1: silver / tetrahydrofuran / 5 h / 20 °C / Inert atmosphere

With hydrogenchloride; iodine; silver; magnesium; calcium chloride; In tetrahydrofuran; benzene;

DOI:10.1007/s11164-018-3282-7

upstream raw materials:

9-fluorenone

9-chloro-9-<α(9-fluorenylidene)-benzyl>fluorene

benzene

9-[bromo-(phenyl)methylene]-9H-fluorene

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