(E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol

Base Information

Chemical Name:(E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol
CAS No.:688762-47-2
Molecular Formula:C₁₈H₂₈O₃
Molecular Weight:292.419
Hs Code.:

Synonyms:(E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol

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Chemical Property of (E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol

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Technology Process of (E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol

There total 11 articles about (E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 688762-41-6
(E)-8-(4-methoxy-benzyloxy)-2,6-dimethyl-oct-6-enoic acid ethyl ester

: 688762-47-2
(E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 0 - 20 ℃;
DOI:10.1016/j.tetasy.2004.01.032

Reference yield:

: 824-94-2
p-methoxybenzyl chloride

: 688762-47-2
(E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol

Guidance literature:: Multi-step reaction with 8 steps

1.1: NaH; tetra-n-butyl ammonium iodide / tetrahydrofuran / 1 h / 0 - 20 °C

1.2: 95 percent / tetrahydrofuran / 6 h / Heating

2.1: aq. TBHP; salicylic acid; SeO₂ / CH₂Cl₂ / 48 h / 20 °C

2.2: 65 percent / NaBH₄ / aq. ethanol / 0 °C

3.1: PBr₃

4.1: CuI; LDA / tetrahydrofuran / 2 h / -110 - -30 °C

4.2: 70 percent / tetrahydrofuran / 1 h / -30 °C

5.1: 90 percent / LiAlH₄ / diethyl ether / 0 - 20 °C

6.1: PBr₃

7.1: 15 percent / CuI; LDA / -110 °C

8.1: 90 percent / LiAlH₄ / diethyl ether / 0 - 20 °C

With tert.-butylhydroperoxide; copper(l) iodide; lithium aluminium tetrahydride; selenium(IV) oxide; phosphorus tribromide; tetra-(n-butyl)ammonium iodide; sodium hydride; salicylic acid; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1016/j.tetasy.2004.01.032

Reference yield:

: 556-82-1
3-methyl-2-buten-1-ol

: 688762-47-2
(E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol

Guidance literature:: Multi-step reaction with 8 steps

1.1: NaH; tetra-n-butyl ammonium iodide / tetrahydrofuran / 1 h / 0 - 20 °C

1.2: 95 percent / tetrahydrofuran / 6 h / Heating

2.1: aq. TBHP; salicylic acid; SeO₂ / CH₂Cl₂ / 48 h / 20 °C

2.2: 65 percent / NaBH₄ / aq. ethanol / 0 °C

3.1: PBr₃

4.1: CuI; LDA / tetrahydrofuran / 2 h / -110 - -30 °C

4.2: 70 percent / tetrahydrofuran / 1 h / -30 °C

5.1: 90 percent / LiAlH₄ / diethyl ether / 0 - 20 °C

6.1: PBr₃

7.1: 15 percent / CuI; LDA / -110 °C

8.1: 90 percent / LiAlH₄ / diethyl ether / 0 - 20 °C

With tert.-butylhydroperoxide; copper(l) iodide; lithium aluminium tetrahydride; selenium(IV) oxide; phosphorus tribromide; tetra-(n-butyl)ammonium iodide; sodium hydride; salicylic acid; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1016/j.tetasy.2004.01.032