12-Benzyl-3,3-dimethyl-11-oxa-tricyclo[7.2.1.0^5,10]dodeca-5,9⁽¹²⁾-diene

Base Information

• Chemical Name: 12-Benzyl-3,3-dimethyl-11-oxa-tricyclo[7.2.1.0^5,10]dodeca-5,9⁽¹²⁾-diene
• CAS No.: 108401-36-1
• Molecular Formula: C₂₀H₂₄O
• Molecular Weight: 280.41
• Mol file: 108401-36-1.mol

Synonyms:12-Benzyl-3,3-dimethyl-11-oxa-tricyclo[7.2.1.0^5,10]dodeca-5,9⁽¹²⁾-diene

Chemical Property of 12-Benzyl-3,3-dimethyl-11-oxa-tricyclo[7.2.1.0^5,10]dodeca-5,9⁽¹²⁾-diene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 12-Benzyl-3,3-dimethyl-11-oxa-tricyclo[7.2.1.0^5,10]dodeca-5,9⁽¹²⁾-diene

There total 2 articles about 12-Benzyl-3,3-dimethyl-11-oxa-tricyclo[7.2.1.0^5,10]dodeca-5,9⁽¹²⁾-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

(4,4-Dimethyl-6-prop-2-ynyloxy-2-vinyl-cyclohex-1-enylmethyl)-benzene (108401-35-0) → (1R,10R)-12-Benzyl-3,3-dimethyl-11-oxa-tricyclo[7.2.1.05,10]dodeca-5,9(12)-diene (108401-36-1,121919-06-0)

Guidance literature:

With potassium tert-butylate; In tert-butyl alcohol; at 83 ℃; for 1h; Heating;

DOI:10.1021/ja00196a041

Reference yield: 92.0%

(4,4-Dimethyl-6-prop-2-ynyloxy-2-vinyl-cyclohex-1-enylmethyl)-benzene (108401-35-0) → 12-Benzyl-3,3-dimethyl-11-oxa-tricyclo[7.2.1.05,10]dodeca-5,9(12)-diene (108401-36-1)

Guidance literature:

With potassium tert-butylate; In tert-butyl alcohol;

DOI:10.1016/S0040-4039(00)84950-3

upstream raw materials:

(4,4-Dimethyl-6-prop-2-ynyloxy-2-vinyl-cyclohex-1-enylmethyl)-benzene