3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-L-glycero-α-D-gluco-hexofuranose

Base Information

• Chemical Name: 3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-L-glycero-α-D-gluco-hexofuranose
• CAS No.: 140138-23-4
• Molecular Formula: C₂₈H₄₀O₁₂
• Molecular Weight: 568.618
• Mol file: 140138-23-4.mol

Synonyms:3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-L-glycero-α-D-gluco-hexofuranose

Chemical Property of 3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-L-glycero-α-D-gluco-hexofuranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-L-glycero-α-D-gluco-hexofuranose

There total 6 articles about 3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-L-glycero-α-D-gluco-hexofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-α-D-galacto-hexopyranos-6-ulos-6-yl)-1,2-O-isopropylidene-D-glycero-β-L-ido-hexofuranose (140138-22-3,140223-67-2) → 3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-D-glycero-β-L-ido-hexofuranose (140138-23-4,140223-68-3,140223-69-4,140223-70-7)

Guidance literature:

With sodium tetrahydroborate; In tetrahydrofuran; methanol; for 0.5h; Ambient temperature;

DOI:10.1016/0008-6215(92)84094-9

Reference yield: 35.0%

3-O-benzyl-5-deoxy-5-C-<(E)-7-deoxy-1,2:3,4-di-O-isopropylidene-L-glycero-α-D-galacto-heptopyranos-7-ylidene>-1,2-O-isopropylidene-α-D-xylofuranose (115259-73-9,115304-53-5) → 3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-L-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-L-glycero-α-D-gluco-hexofuranose (140223-69-4) + 3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-L-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-D-glycero-β-L-ido-hexofuranose (140138-23-4,140223-68-3,140223-69-4,140223-70-7)

Guidance literature:

With 4-methylmorpholine N-oxide; osmium(VIII) oxide; In tetrahydrofuran; water; tert-butyl alcohol; Ambient temperature;

DOI:10.1016/0008-6215(92)84094-9

Reference yield: 15.1%

3-O-benzyl-5-deoxy-5-C-<(E)-7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7-ylidene>-1,2-O-isopropylidene-α-D-xylofuranose (115259-73-9,115304-53-5) → 3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-L-glycero-α-D-gluco-hexofuranose (140138-23-4) + 3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-hexopyranos-6-yl)-1,2-O-isopropylidene-D-glycero-β-L-ido-hexofuranose (140138-23-4,140223-68-3,140223-69-4,140223-70-7)

Guidance literature:

With 4-methylmorpholine N-oxide; osmium(VIII) oxide; In tetrahydrofuran; water; tert-butyl alcohol; Ambient temperature;

DOI:10.1016/0008-6215(92)84094-9

upstream raw materials:

3-O-benzyl-5-deoxy-5-C-<(E)-7-deoxy-1,2:3,4-di-O-isopropylidene-D-glycero-α-D-galacto-heptopyranos-7-ylidene>-1,2-O-isopropylidene-α-D-xylofuranose

3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-α-D-galacto-hexopyranos-6-ulos-6-yl)-1,2-O-isopropylidene-L-glycero-α-D-gluco-hexofuranose

3-O-benzyl-6-C-(1,2:3,4-di-O-isopropylidene-α-D-galacto-hexopyranos-6-ulos-6-yl)-1,2-O-isopropylidene-D-glycero-β-L-ido-hexofuranose

3-O-benzyl-5-deoxy-5-C-<(E)-7-deoxy-1,2:3,4-di-O-isopropylidene-L-glycero-α-D-galacto-heptopyranos-7-ylidene>-1,2-O-isopropylidene-α-D-xylofuranose