5,10,15-tri(3,5-tBu₂C₆H₃)-Cl₂-Pd(II)-diporphyrin

Base Information

• Chemical Name: 5,10,15-tri(3,5-tBu₂C₆H₃)-Cl₂-Pd(II)-diporphyrin
• CAS No.: 262424-46-4
• Molecular Formula: C₁₂₄H₁₃₈Cl₂N₈Pd₂
• Molecular Weight: 2024.26

Synonyms:5,10,15-tri(3,5-tBu₂C₆H₃)-Cl₂-Pd(II)-diporphyrin

Chemical Property of 5,10,15-tri(3,5-tBu₂C₆H₃)-Cl₂-Pd(II)-diporphyrin

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Technology Process of 5,10,15-tri(3,5-tBu₂C₆H₃)-Cl₂-Pd(II)-diporphyrin

There total 3 articles about 5,10,15-tri(3,5-tBu₂C₆H₃)-Cl₂-Pd(II)-diporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

5,10,15-tri(3,5-tBuC5H3)-Pd(II)-porphyrin (262424-43-1) → 5,10,15-tri(3,5-tBu2C6H3)-Cl2-Pd(II)-diporphyrin (262424-46-4) + Pd(5,10,15-tri(3,5-di-tert-butylphenyl)-20-bromoporphyrin) (262424-47-5)

Guidance literature:

With (BrC₆H₄)3NHSbCl₆; In chloroform; Pd commplex was oxidized by the hexachloroantimonate (3 equiv.) in CHCl3for 48 h; the product distribu. is depended on the react. time and the amounts of the hexachloroantimonate; the products were sepd. by SEC and then by chromy. (silica gel, hexane/CH2Cl2);

DOI:10.1021/ja0110933

Reference yield: 49.0%

5,10,15-tri(3,5-tBuC5H3)-Pd(II)-porphyrin (262424-43-1) + tris-(4-bromophenyl)aminium hexachloroantimonate → 5,10,15-tri(3,5-tBu2C6H3)-Cl2-Pd(II)-diporphyrin (262424-46-4)

Guidance literature:

In chloroform; byproducts: Pd(C20N4H8)(C14H21)3Br; to soln. of 5,10,15-triaryl-Pd(II)-porphyrin in CHCl3 added 3 equiv tris(4-bromophenyl)aminium hexachloroantimonate; mixt. stirred for 12 h at room temp.; diluted with water and dried;; cromy.;elution with hexane/CH2Cl2; MS;

DOI:10.1002/(SICI)1521-3773(20000204)39:3<558::AID-ANIE558>3.0.CO;2-G

Reference yield: 20.0%

5,10,15-tri(3,5-tBuC5H3)-Pd(II)-porphyrin (262424-43-1) + tris-(4-bromophenyl)aminium hexachloroantimonate → 5,10,15-tri(3,5-tBu2C6H3)-Cl2-Pd(II)-diporphyrin (262424-46-4) + 5,10,15-tri(3,5-tBu2C6H3)-Cl-Pd(II)-diporphyrin (262424-45-3) + 5,10,15-tri(3,5-tBu2C6H3)-Pd(II)-diporphyrin (262424-44-2)

Guidance literature:

In chloroform; to soln. of 5,10,15-triaryl-Pd(II)-porphyrin in CHCl3 added tris(4-bromophenyl)aminium hexachloroantimonate; mixt. stirred for 12 h at room temp.; diluted with water and dried; ratio depends on react. time and amt. of ligand; cromy.; elution with hexane/CH2Cl2; MS, NMR;

DOI:10.1002/(SICI)1521-3773(20000204)39:3<558::AID-ANIE558>3.0.CO;2-G

upstream raw materials:

5,10,15-tri(3,5-tBuC₅H₃)-Pd(II)-porphyrin

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