phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside

Base Information

Chemical Name:phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside
CAS No.:241490-68-6
Molecular Formula:C₂₂H₂₇NO₄S
Molecular Weight:401.527
Hs Code.:

Synonyms:phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside

Suppliers and Price of phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside

There total 2 articles about phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 108-24-7
acetic anhydride

: 241490-66-4
phenyl 3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside

: 241490-68-6
phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside

Guidance literature:: With pyridine; In chloroform; for 6h; Heating;
DOI:10.1021/jo990403l

Reference yield:

: O-benzyl phenyl-2,6-dideoxy-1-thio-α,β-erythro-hexopyranosid-3-ulose oxime

: 241490-68-6
phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: cerium trichloride / tetrahydrofuran; diethyl ether / -78 °C

1.2: 42 percent / tetrahydrofuran; diethyl ether / -78 - -50 °C

2.1: 79 percent / pyridine / CHCl₃ / 6 h / Heating

With pyridine; cerium(III) chloride; In tetrahydrofuran; diethyl ether; chloroform; 1.1: Substitution / 1.2: Methylation / 2.1: Acetylation;
DOI:10.1021/jo990403l

Reference yield: 31.0%

: 98750-47-1
methyl 3-O-benzyl-2,6-dideoxy-α-L-lyxo-hexopyranoside

: 241490-68-6
phenyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside

: 241490-71-1
methyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-α-L-ribo-hexopyranosyl-(1->4)-3-O-benzyl-2,6-dideoxy-α-L-lyxo-hexopyranoside

: 241490-72-2
methyl 4-O-acetyl-3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-β-L-ribo-hexopyranosyl-(1->4)-3-O-benzyl-2,6-dideoxy-α-L-lyxo-hexopyranoside

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; In diethyl ether; 1,2-dichloro-ethane; at -20 - 10 ℃; for 2h;
DOI:10.1021/jo990403l