(2R)-N-{(E)-3-[((2E)-6-(tert-butyldiphenysilyloxy)-3-methylhex-2-en-1-yl)oxy]acryloyl}bornane-10,2-sultam

Base Information

Chemical Name:(2R)-N-{(E)-3-[((2E)-6-(tert-butyldiphenysilyloxy)-3-methylhex-2-en-1-yl)oxy]acryloyl}bornane-10,2-sultam
CAS No.:1425677-59-3
Molecular Formula:C₃₆H₄₉NO₅SSi
Molecular Weight:635.94
Hs Code.:

Synonyms:(2R)-N-{(E)-3-[((2E)-6-(tert-butyldiphenysilyloxy)-3-methylhex-2-en-1-yl)oxy]acryloyl}bornane-10,2-sultam

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R)-N-{(E)-3-[((2E)-6-(tert-butyldiphenysilyloxy)-3-methylhex-2-en-1-yl)oxy]acryloyl}bornane-10,2-sultam

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Technology Process of (2R)-N-{(E)-3-[((2E)-6-(tert-butyldiphenysilyloxy)-3-methylhex-2-en-1-yl)oxy]acryloyl}bornane-10,2-sultam

There total 1 articles about (2R)-N-{(E)-3-[((2E)-6-(tert-butyldiphenysilyloxy)-3-methylhex-2-en-1-yl)oxy]acryloyl}bornane-10,2-sultam which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 187336-22-7
(E)-6-(tert-butyldiphenylsilyloxy)-3-methylhex-2-en-1-ol

: 775321-08-9
(1S,5R,7R)-1-(10,10-dimethyl-3,3-dioxo-3-thia-4-aza-tricyclo[5.2.1.0^1,5]decane-4-yl)-2-propyn-1-one

: 1425677-59-3
(2R)-N-{(E)-3-[((2E)-6-(tert-butyldiphenysilyloxy)-3-methylhex-2-en-1-yl)oxy]acryloyl}bornane-10,2-sultam

Guidance literature:: With tributylphosphine; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;
DOI:10.3390/molecules171113330

Reference yield: 72.0%

: 1425677-59-3
(2R)-N-{(E)-3-[((2E)-6-(tert-butyldiphenysilyloxy)-3-methylhex-2-en-1-yl)oxy]acryloyl}bornane-10,2-sultam

: 1425677-62-8
(2R)-N-[(2R,3S)-6-(tert-butyldiphenysilyloxy)-2-formyl-3-methyl-3-vinylhexanoyl]bornane-10,2-sultam

: 1425677-65-1
(2R)-N-[(2S,3R)-6-(tert-butyldiphenysilyloxy)-2-formyl-3-methyl-3-vinylhexanoyl]bornane-10,2-sultam

Guidance literature:: With 2,6-di-tert-butyl-4-methyl-phenol; In toluene; at 140 ℃; for 71h; stereoselective reaction; Sealed tube;
DOI:10.3390/molecules171113330

Reference yield:

: 1425677-59-3
(2R)-N-{(E)-3-[((2E)-6-(tert-butyldiphenysilyloxy)-3-methylhex-2-en-1-yl)oxy]acryloyl}bornane-10,2-sultam

: 1425677-85-5
(2R)-N-[(2R,3S)-2-(acetoxymethyl)-6-(tert-butyldiphenysilyloxy)-3-methyl-3-vinylhexanoyl]bornane-10,2-sultam

Guidance literature:: Multi-step reaction with 3 steps

1: 2,6-di-tert-butyl-4-methyl-phenol / toluene / 71 h / 140 °C / Sealed tube

2: sodium tetrahydroborate / ethanol / 4 h / 0 °C

3: triethylamine; dmap / dichloromethane / 2.5 h / 0 - 20 °C

With dmap; sodium tetrahydroborate; 2,6-di-tert-butyl-4-methyl-phenol; triethylamine; In ethanol; dichloromethane; toluene; 1: |Claisen Rearrangement;
DOI:10.3390/molecules171113330