C₃₆H₃₂N₄O₁₂S

Base Information

• Chemical Name: C₃₆H₃₂N₄O₁₂S
• CAS No.: 1431429-89-8
• Molecular Formula: C₃₆H₃₂N₄O₁₂S
• Molecular Weight: 744.736
• Mol file: 1431429-89-8.mol

Synonyms:C₃₆H₃₂N₄O₁₂S

Chemical Property of C₃₆H₃₂N₄O₁₂S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₃₂N₄O₁₂S

There total 5 articles about C₃₆H₃₂N₄O₁₂S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C40H40N4O12S (1431429-96-7) → C36H32N4O12S (1431429-89-8)

Guidance literature:

With phenylsilane; trifluoroacetic acid; In dichloromethane; for 2.5h; Inert atmosphere;

DOI:10.1021/ja4014024

Reference yield:

4-nitrobenzyl chloroformate (4457-32-3) → C36H32N4O12S (1431429-89-8)

Guidance literature:

Multi-step reaction with 5 steps

1.1: sodium carbonate / water; acetonitrile / 15 h / Cooling with ice; Inert atmosphere

2.1: sodium hydrogencarbonate / N,N-dimethyl-formamide / 21 h / Inert atmosphere

3.1: chlorotriisopropylsilane; trifluoroacetic acid / dichloromethane / 1.5 h / Inert atmosphere

4.1: sodium hydrogencarbonate; tetrabutylammomium bromide / water; ethyl acetate / 5 h / pH 8.5 / Inert atmosphere

4.2: 15 h / Inert atmosphere

5.1: trifluoroacetic acid; phenylsilane / dichloromethane / 2.5 h / Inert atmosphere

With chlorotriisopropylsilane; phenylsilane; tetrabutylammomium bromide; sodium hydrogencarbonate; sodium carbonate; trifluoroacetic acid; In dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; acetonitrile;

DOI:10.1021/ja4014024

Reference yield:

C30H26N2O6S → C36H32N4O12S (1431429-89-8)

Guidance literature:

Multi-step reaction with 4 steps

1.1: sodium hydrogencarbonate / N,N-dimethyl-formamide / 21 h / Inert atmosphere

2.1: chlorotriisopropylsilane; trifluoroacetic acid / dichloromethane / 1.5 h / Inert atmosphere

3.1: sodium hydrogencarbonate; tetrabutylammomium bromide / water; ethyl acetate / 5 h / pH 8.5 / Inert atmosphere

3.2: 15 h / Inert atmosphere

4.1: trifluoroacetic acid; phenylsilane / dichloromethane / 2.5 h / Inert atmosphere

With chlorotriisopropylsilane; phenylsilane; tetrabutylammomium bromide; sodium hydrogencarbonate; trifluoroacetic acid; In dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide;

DOI:10.1021/ja4014024

upstream raw materials:

4-nitrobenzyl chloroformate

C₃₇H₃₁N₃O₈S

N-p-nitrobenzyloxycarbonyl-D-cysteine p-nitrobenzyl ester

C₄₀H₄₀N₄O₁₂S