<5-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2α,3β,4β,5α-tetrahydro-3,4-dihydroxy-2H-pyran-2-yl>-2-propanone

Base Information

Chemical Name:<5-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2α,3β,4β,5α-tetrahydro-3,4-dihydroxy-2H-pyran-2-yl>-2-propanone
CAS No.:86611-21-4
Molecular Formula:C₂₆H₃₆O₅Si
Molecular Weight:456.654
Hs Code.:

Synonyms:<5-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2α,3β,4β,5α-tetrahydro-3,4-dihydroxy-2H-pyran-2-yl>-2-propanone

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Chemical Property of <5-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2α,3β,4β,5α-tetrahydro-3,4-dihydroxy-2H-pyran-2-yl>-2-propanone

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Technology Process of <5-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2α,3β,4β,5α-tetrahydro-3,4-dihydroxy-2H-pyran-2-yl>-2-propanone

There total 24 articles about <5-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2α,3β,4β,5α-tetrahydro-3,4-dihydroxy-2H-pyran-2-yl>-2-propanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 80502-35-8
5α-<2-ethyl>-5,6-dihydro-2H-pyran-2α-ylpropan-2-one

: 86611-21-4
<5-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2α,3β,4β,5α-tetrahydro-3,4-dihydroxy-2H-pyran-2-yl>-2-propanone

Guidance literature:: With 4-methylmorpholine N-oxide; osmium(VIII) oxide; In water; acetone; at 25 ℃; for 24h;
DOI:10.1021/jo00166a013

Reference yield:

: 86611-19-0,86611-20-3
5α-<2-ethyl>-5,6-dihydro-2H-pyran-2α-ylpropan-2-ol

: 86611-21-4
<5-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2α,3β,4β,5α-tetrahydro-3,4-dihydroxy-2H-pyran-2-yl>-2-propanone

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / pyridinium chlorochromate / CH₂Cl₂ / 4 h

2: OsO₄, N-methylmorpholine N-oxide / 2-methyl-propan-2-ol / 27 h / Heating

With osmium(VIII) oxide; 4-methylmorpholine N-oxide; pyridinium chlorochromate; In dichloromethane; tert-butyl alcohol;

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 86611-21-4
<5-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2α,3β,4β,5α-tetrahydro-3,4-dihydroxy-2H-pyran-2-yl>-2-propanone

Guidance literature:: Multi-step reaction with 3 steps

1: Et₃N, Me₂NC₅H₄N

2: pyridinium CrO₃Cl

3: OsO₄, N-methylmorpholine N-oxide

With osmium(VIII) oxide; Me₂NC₅H₄N; 4-methylmorpholine N-oxide; triethylamine; pyridinium chlorochromate;
DOI:10.1021/ja00368a042