2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside

Base Information

Chemical Name:2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside
CAS No.:1252764-10-5
Molecular Formula:C₃₁H₃₈IN₃O₁₆
Molecular Weight:835.558
Hs Code.:

Synonyms:2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside

Suppliers and Price of 2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside

There total 5 articles about 2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1252764-09-2
2-deoxy-2-azido-1α-trichloroacetamido-hexa-O-acetyl cellobioside

: 57455-06-8
3-iodobenzylalcohol

: 1252764-10-5
2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -15 ℃; for 1h; Inert atmosphere; Molecular sieve;
DOI:10.1080/07328303.2010.508142

Reference yield:

: 225242-63-7
3,6-di-O-acetyl-2-azido-2-deoxy-4-O-(tetra-O-acetyl-β-D-glucopyranosyl)-α-β-D-glucopyranosyl nitrate

: 1252764-10-5
2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside

Guidance literature:: Multi-step reaction with 3 steps

1: water; sodium nitrite / 1,4-dioxane / 6 h / 80 °C

2: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 2 h / 20 °C / Inert atmosphere

3: boron trifluoride diethyl etherate / dichloromethane / 1 h / -15 °C / Inert atmosphere; Molecular sieve

With boron trifluoride diethyl etherate; water; 1,8-diazabicyclo[5.4.0]undec-7-ene; sodium nitrite; In 1,4-dioxane; dichloromethane;
DOI:10.1080/07328303.2010.508142

Reference yield:

: 67314-36-7
3,6-di-O-acetyl-4-[2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl]-2-deoxy-D-arabino-hex-1-enopyranose

: 1252764-10-5
2-deoxy-2-azido-1β-(m-iodo)benzyl-hexa-O-acetyl cellobioside

Guidance literature:: Multi-step reaction with 4 steps

1: ammonium cerium (IV) nitrate; sodium azide / acetonitrile / 12 h / -30 - 20 °C / Inert atmosphere

2: water; sodium nitrite / 1,4-dioxane / 6 h / 80 °C

3: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 2 h / 20 °C / Inert atmosphere

4: boron trifluoride diethyl etherate / dichloromethane / 1 h / -15 °C / Inert atmosphere; Molecular sieve

With sodium azide; ammonium cerium (IV) nitrate; boron trifluoride diethyl etherate; water; 1,8-diazabicyclo[5.4.0]undec-7-ene; sodium nitrite; In 1,4-dioxane; dichloromethane; acetonitrile;
DOI:10.1080/07328303.2010.508142